Home
Class 11
CHEMISTRY
When two AO s combine energy of bonding ...

When two `AO` s combine energy of bonding `MO` is lowered by x while of antibonding `MO` is raised by y Then .

A

`x =y`

B

`x lt y`

C

`x gt y`

D

Can be any of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the changes in energy when two atomic orbitals combine to form molecular orbitals. ### Step-by-Step Solution: 1. **Understanding Molecular Orbital Theory**: - When two atomic orbitals (AOs) combine, they form two types of molecular orbitals (MOs): bonding and antibonding. The bonding molecular orbital (MO) is lower in energy than the original atomic orbitals, while the antibonding MO is higher in energy. 2. **Energy Changes**: - According to the problem, the energy of the bonding MO is lowered by a value \(X\). - Simultaneously, the energy of the antibonding MO is raised by a value \(Y\). 3. **Conservation of Energy Principle**: - The principle of conservation of energy states that the total energy of a closed system remains constant. Therefore, any decrease in energy in one part of the system must be balanced by an equal increase in energy in another part. 4. **Setting Up the Equation**: - Since the bonding MO's energy decreases by \(X\) and the antibonding MO's energy increases by \(Y\), we can express this relationship as: \[ \text{Total Energy Change} = \text{Change in Bonding MO} + \text{Change in Antibonding MO} \] - This can be written as: \[ -X + Y = 0 \] - Rearranging gives us: \[ Y = X \] 5. **Conclusion**: - From the above analysis, we conclude that the decrease in energy of the bonding MO (\(X\)) is equal to the increase in energy of the antibonding MO (\(Y\)). Therefore, the correct answer is: \[ X = Y \] ### Final Answer: - \(X\) is equal to \(Y\).
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct (Miscellaneous)|23 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assetion Reasoning|30 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct (Resonance And Formal Charges)|10 Videos
  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Concept Applicationexercise(4.3)|19 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective type|1 Videos

Similar Questions

Explore conceptually related problems

Comprehension given below is followed by some multiple choice question, Each question has one correct options. Choose the correct option. Molecular orbitals are formed by the overlap of atomic orbitals. Two atomic orbitals combine to form two molecular orbitals called bonding molecular orbital (BMO) and anti-bonding molecular orbital (ABMO). Energy of anti-bonding orbital is raised above the parent atomic orbitals that have combined and hte energy of the bonding orbital is lowered than the parent atomic orbitals. energies of various molecular orbitals for elements hydrogen to nitrogen increase in the order sigma1s lt sigma^(star)1s lt sigma^(star)2s lt ((pi2p_(x))=(pi2p_(y))) lt sigma2p_(z) lt (pi^(star)2p_(x) = pi^(star)2p_(y)) lt sigma^(star)2p_(z) and For oxygen and fluorine order of enregy of molecules orbitals is given below. sigma1s lt sigma^(star)1s lt sigma2s lt sigma^(star)2s lt sigmap_(z) lt (pi2p_(x) ~~ pi2p_(y)) lt (pi^(star)2p_(x)~~ pi^(star)2py) lt sigma^(star)2p_(z) Different atomic orbitalsof one atom combine with those atoms orbitals of the second atom which have comparable energies and proper orientation. Further, if the overlapping is head on, the molecular orbital is called sigma, sigma andif the overlap is lateral, the molecular orbital is called pi, pi . The molecular orbitals are filled with electrons according to the same rules as followed for filling of atomic orbitals. However, the order for filling is not the same for all molecules or their ions. Bond order is one of the most important parameters to compare the strength of bonds. 67) Which of the following pair is expected to have the same bond order?

Comprehension given below is followed by some multiple choice question, Each question has one correct options. Choose the correct option. Molecular orbitals are formed by the overlap of atomic orbitals. Two atomic orbitals combine to form two molecular orbitals called bonding molecular orbital (BMO) and anti-bonding molecular orbital (ABMO). Energy of anti-bonding orbital is raised above the parent atomic orbitals that have combined and hte energy of the bonding orbital is lowered than the parent atomic orbitals. energies of various molecular orbitals for elements hydrogen to nitrogen increase in the order sigma1s lt sigma^(star)1s lt sigma^(star)2s lt ((pi2p_(x))=(pi2p_(y))) lt sigma2p_(z) lt (pi^(star)2p_(x) = pi^(star)2p_(y)) lt sigma^(star)2p_(z) and For oxygen and fluorine order of enregy of molecules orbitals is given below. sigma1s lt sigma^(star)1s lt sigma2s lt sigma^(star)2s lt sigmap_(z) lt (pi2p_(x) ~~ pi2p_(y)) lt (pi^(star)2p_(x)~~ pi^(star)2py) lt sigma^(star)2p_(z) Different atomic orbitalsof one atom combine with those atoms orbitals of the second atom which have comparable energies and proper orientation. Further, if the overlapping is head on, the molecular orbital is called sigma, sigma andif the overlap is lateral, the molecular orbital is called pi, pi . The molecular orbitals are filled with electrons according to the same rules as followed for filling of atomic orbitals. However, the order for filling is not the same for all molecules or their ions. Bond order is one of the most important parameters to compare the strength of bonds. 67) Which of the following pair is expected to have the same bonod order?

Comprehension given below is followed by some multiple choice question, Each question has one correct options. Choose the correct option. Molecular orbitals are formed by the overlap of atomic orbitals. Two atomic orbitals combine to form two molecular orbitals called bonding molecular orbital (BMO) and anti-bonding molecular orbital (ABMO). Energy of anti-bonding orbital is raised above the parent atomic orbitals that have combined and hte energy of the bonding orbital is lowered than the parent atomic orbitals. energies of various molecular orbitals for elements hydrogen to nitrogen increase in the order sigma1s lt sigma^(star)1sltsigma^(star)2slt((pi2p_(x))=(pi2p_(y)))ltsigma2p_(z)lt(pi^(star)2p_(x) = pi^(star)2p_(y))ltsigma^(star)2p_(z) and For oxygen and fluorine order of enregy of molecules orbitals is given below. sigma1s lt sigma^(star)1s lt sigma2s lt sigma^(star)2s lt sigmap_(z) lt (pi2p_(x) ~~ pi2p_(y)) lt (pi^(star)2p_(x)~~ pi^(star)2py) lt sigma^(star)2p_(z) Different atomic orbitalsof one atom combine with those atoms orbitals of the second atom which have comparable energies and proper orientation. Further, if the overlapping is head on, the molecular orbital is called sigma, sigma andif the overlap is lateral, the molecular orbital is called pi, pi . The molecular orbitals are filled with electrons according to the same rules as followed for filling of atomic orbitals. However, the order for filling is not the same for all molecules or their ions. Bond order is one of the most important parameters to compare the strength of bonds. In which of the following molecules, sigma2p_(z) molecular orbital is filled after pi2p_(x) and pi2p_(y) molecular orbitals?

Comprehension given below is followed by some multiple choice question, Each question has one correct options. Choose the correct option. Molecular orbitals are formed by the overlap of atomic orbitals. Two atomic orbitals combine to form two molecular orbitals called bonding molecular orbital (BMO) and anti-bonding molecular orbital (ABMO). Energy of anti-bonding orbital is raised above the parent atomic orbitals that have combined and hte energy of the bonding orbital is lowered than the parent atomic orbitals. energies of various molecular orbitals for elements hydrogen to nitrogen increase in the order sigma1s lt sigma^(star)1sltsigma^(star)2slt((pi2p_(x))=(pi2p_(y)))ltsigma2p_(z)lt(pi^(star)2p_(x) = pi^(star)2p_(y))ltsigma^(star)2p_(z) and For oxygen and fluorine order of enregy of molecules orbitals is given below. sigma1s lt sigma^(star)1s lt sigma2s lt sigma^(star)2s lt sigmap_(z) lt (pi2p_(x) ~~ pi2p_(y)) lt (pi^(star)2p_(x)~~ pi^(star)2py) lt sigma^(star)2p_(z) Different atomic orbitalsof one atom combine with those atoms orbitals of the second atom which have comparable energies and proper orientation. Further, if the overlapping is head on, the molecular orbital is called sigma, sigma andif the overlap is lateral, the molecular orbital is called pi, pi . The molecular orbitals are filled with electrons according to the same rules as followed for filling of atomic orbitals. However, the order for filling is not the same for all molecules or their ions. Bond order is one of the most important parameters to compare the strength of bonds. 66) Which of the following moleculart orbitals has maximum number of nodal planes?

Out of bonding and antibonding M.O, which is filled first and why?

When two A.O. combine they form B.MO & ABMO. During BMO .x. energy is released & during ABMO .y. energy is absorbed. So the correct relation will be :-

In MO energy diagram for heteronuclear diatomic molecule is similar However, the energies of the AO s of the atom having higher atomic number being lower, the diagram will be unsymmetrical, but that will not make a difference in the electron count The bond order is half the difference in the number of electrns of the bonding (sigma and pi) and anti-bonding (sigma and pi) MO s For a bond to have been formed the bond order the shorter is the bond distance and the greater is the bond dissociation energey But if the bond order is smae in the above two cases, then the bond distance will be greater and the bond dissocation energy smaller in the case which has more populated anti-bonding orbitals The presence of unpaired electron(s) in a molecualr orbital will make the system paramagnetic Which of the following orders is correct in respect of bond dissociation energey ? .

In MO energy diagram for heteronuclear diatomic molecule is similar However, the energies of the AO s of the atom having higher atomic number being lower, the diagram will be unsymmetrical, but that will not make a difference in the electron count The bond order is half the difference in the number of electrns of the bonding (sigma and pi) and anti-bonding (sigma and pi) MO s For a bond to have been formed the bond order the shorter is the bond distance and the greater is the bond dissociation energey But if the bond order is smae in the above two cases, then the bond distance will be greater and the bond dissocation energy smaller in the case which has more populated anti-bonding orbitals The presence of unpaired electron(s) in a molecualr orbital will make the system paramagnetic Which among the following will have a triple bond order ? .

In MO energy diagram for heteronuclear diatomic molecule is similar However, the energies of the AO s of the atom having higher atomic number being lower, the diagram will be unsymmetrical, but that will not make a difference in the electron count The bond order is half the difference in the number of electrns of the bonding (sigma and pi) and anti-bonding (sigma and pi) MO s For a bond to have been formed the bond order the shorter is the bond distance and the greater is the bond dissociation energey But if the bond order is smae in the above two cases, then the bond distance will be greater and the bond dissocation energy smaller in the case which has more populated anti-bonding orbitals The presence of unpaired electron(s) in a molecualr orbital will make the system paramagnetic Which of the following species is not expected to exist ? .

In MO energy diagram for heteronuclear diatomic molecule is similar However, the energies of the AO s of the atom having higher atomic number being lower, the diagram will be unsymmetrical, but that will not make a difference in the electron count The bond order is half the difference in the number of electrns of the bonding (sigma and pi) and anti-bonding (sigma and pi) MO s For a bond to have been formed the bond order the shorter is the bond distance and the greater is the bond dissociation energey But if the bond order is smae in the above two cases, then the bond distance will be greater and the bond dissocation energy smaller in the case which has more populated anti-bonding orbitals The presence of unpaired electron(s) in a molecualr orbital will make the system paramagnetic Which of the following species is expected to be paramagnetic ? .

CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises Single Correct (Molecular Orbital Theory (Mot))
  1. The species which does not show paramagnetism is .

    Text Solution

    |

  2. Which of the following cannot exist on the basic of MO theory ? .

    Text Solution

    |

  3. Which one paramagnetic and has a bond order of 0.5 ? .

    Text Solution

    |

  4. The bond energies NO,NO^(+) and NO^(Theta) ion follows the order

    Text Solution

    |

  5. In the MO diagram for O(2)^(Theta) ion the highest occupied orbital is...

    Text Solution

    |

  6. Which of the following is not diamagnetic ? .

    Text Solution

    |

  7. The bond order of CO and NO is .

    Text Solution

    |

  8. Combination of two AO s lead to the formation of .

    Text Solution

    |

  9. The possible molecular orbital formed when two d-orbitals overlap is .

    Text Solution

    |

  10. Which of the following species exhibits the diamagnetic behaviour?

    Text Solution

    |

  11. Which of the following species is paramagnetic ? .

    Text Solution

    |

  12. The bond order in NO is 2.5 while that in NO^(o+) is 3 Which of the fo...

    Text Solution

    |

  13. When two AO s combine energy of bonding MO is lowered by x while of an...

    Text Solution

    |

  14. In Which of the following the double bond consist of the pi bonds .

    Text Solution

    |

  15. Which of the following MOs has more than one nodal plane?

    Text Solution

    |

  16. Which of the following MO's has zero nodal planes ? .

    Text Solution

    |

  17. The main axis of diatomic molecule is z. The orbitals px and py overla...

    Text Solution

    |

  18. The paramagnetic property of the oxygen molecule is due to the presenc...

    Text Solution

    |

  19. Which of the following combination is not allowed in the LCAO method f...

    Text Solution

    |

  20. The energy of sigma(2s), is greater than that of sigma(1s)^** orbital ...

    Text Solution

    |