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Which is a correct statement about dibor...

Which is a correct statement about diborane structure ? .

A

All `HBH` bond angles are equal

B

`All -H -B` bond lenghts are equal

C

it has two three-center-2 electron bonds

D

All hydrogen and boron atoms are in one plane

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To solve the question regarding the correct statement about the structure of diborane (B2H6), we will analyze the structure and properties of diborane step by step. ### Step-by-Step Solution: 1. **Understanding Diborane**: - Diborane is a chemical compound with the formula B2H6. It consists of two boron (B) atoms and six hydrogen (H) atoms. 2. **Hybridization of Boron**: - In diborane, boron atoms undergo sp3 hybridization. Each boron atom forms three bonds with hydrogen atoms, leading to a unique bonding situation. 3. **Formation of the Structure**: - Each boron atom in diborane forms three B-H bonds. However, two of these bonds are not typical covalent bonds; they are referred to as "banana bonds" or three-center two-electron bonds. This occurs due to the presence of an empty p-orbital on each boron atom that overlaps with the hydrogen atoms. 4. **Geometric Arrangement**: - The structure of diborane is not planar. The two boron atoms are connected by two hydrogen atoms that lie in a plane, while the remaining four hydrogen atoms are arranged such that two are in the same plane as the boron atoms and two are above and below this plane, creating a three-dimensional shape. 5. **Bond Angles and Lengths**: - The bond angles in diborane are not all equal. The H-B-H bond angles for the hydrogen atoms in the plane are approximately 120 degrees, while the bond angles involving the hydrogen atoms above and below the plane differ. 6. **Conclusion**: - Based on the analysis, the correct statement about diborane structure is that not all H-B-H bond angles are equal, and the bond lengths of B-H bonds are also not equal due to the varying nature of the bonding. ### Final Answer: The correct statement about diborane structure is that **the bond angles are not equal and the bond lengths are not equal**.

To solve the question regarding the correct statement about the structure of diborane (B2H6), we will analyze the structure and properties of diborane step by step. ### Step-by-Step Solution: 1. **Understanding Diborane**: - Diborane is a chemical compound with the formula B2H6. It consists of two boron (B) atoms and six hydrogen (H) atoms. 2. **Hybridization of Boron**: ...
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises Single Correct (Miscellaneous)
  1. If one assume linear structure instead of bent structure for water the...

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  2. Which is the wrong order for the stated property ? .

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  3. Which is a correct statement about diborane structure ? .

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  4. For overset(Theta)NH(2) the best three-dimensional view is .

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  5. The set representing the correct order of ionic radius is

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  6. Which of the following are not isoelectronic speices ?

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  7. The EN's of F, CI Br and I are 4.0 ,3.0, 2.8 and 2.5 respectively The ...

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  8. The C -C bond length is 1.54 Å C =C bond length is 1.33 Å What is the ...

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  9. The correct order of the thermal stability of hydrogen halides (H-X) i...

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  10. Which of following statement is correct ? .

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  11. The valuse of EN of atoms A and B are 1.80 and 4.0 respectively The pe...

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  12. The statement true for N(3)^(-) is

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  13. The decreasing (O -O) bonf length order in the following is .

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  14. Which of the following substance has the highest melting point? .

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  15. Which of the following statement is correct ? .

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  16. Which of the following bonds is the strongest ? .

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  17. The molecule having highest bond enegy is

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  18. Which set is expected to show the smallest difference in IE(1) ?

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  19. Which of the following statement is wrong ? .

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  20. Which of the following is correct ?

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