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Assertion : (CH(3))(3)N geometry is pyra...

Assertion : `(CH_(3))_(3)N` geometry is pyramidal but in case `(SiH_(3))_(3)N` it is planar.
Reason :The maximum covalency of Si is six but that of C is four.

A

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`

B

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`

C

If `(A)` is correct but `(R )` is incorrect

D

If `(A)` is incorrect but `(R )` is correct

Text Solution

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The correct Answer is:
B

Both `(A)` and `(R )` are correct but `(R )` is not the correct explanation of `(A)` Geometry of `(CH_(3))_(3)overset(..)N` is pyramidal due to non-availability of d-orbitals in `C` whereas geometry of `(SiH_(3))_(3)overset(..)H` is planar due to availility of d-orbitals in Si and it froms (p pi-d pi) back bonding .
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