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Assertion O(2) and N(2)^(2-) have same n...

Assertion `O_(2)` and `N_(2)^(2-)` have same number of electrons and same molecular orbital configuration
Reasoning `O_(2)` and `N_(2)^(2-)` have the same bond order .

A

If both `(A)` and `(R )` are correct and `(R )` is the correct
explanation of `(A)`

B

If both `(A)` and `(R )` are correct and `(R )` is the correct
explanation of `(A)`

C

If `(A)` is correct but `(R )` is incorrect

D

If `(A)` is incorrect but `(R )` is correct

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and reasoning provided: **Assertion**: O₂ and N₂²⁻ have the same number of electrons and the same molecular orbital configuration. **Reasoning**: O₂ and N₂²⁻ have the same bond order. ### Step-by-Step Solution: 1. **Determine the Number of Electrons**: - O₂ has 8 electrons (4 from each oxygen atom). - N₂²⁻ has 7 electrons from each nitrogen atom (total 14) plus 2 additional electrons due to the -2 charge, giving a total of 16 electrons. - Therefore, both O₂ and N₂²⁻ have 16 electrons. 2. **Molecular Orbital Configuration**: - For O₂, the molecular orbital configuration is: - σ1s², σ*1s², σ2s², σ*2s², σ2p_z², π2p_x², π2p_y², π*2p_x¹, π*2p_y¹. - For N₂²⁻, the molecular orbital configuration is: - σ1s², σ*1s², σ2s², σ*2s², π2p_x², π2p_y², σ2p_z², π*2p_x¹, π*2p_y¹. - Comparing the configurations, we see that they are not the same. The order of filling is different, especially in the 2p orbitals. 3. **Bond Order Calculation**: - Bond order is calculated using the formula: \[ \text{Bond Order} = \frac{1}{2} (N_B - N_A) \] where \( N_B \) is the number of bonding electrons and \( N_A \) is the number of antibonding electrons. - For O₂: - Bonding electrons: 10 (σ1s² + σ2s² + σ2p_z² + π2p_x² + π2p_y²) - Antibonding electrons: 6 (σ*1s² + σ*2s² + π*2p_x¹ + π*2p_y¹) - Bond order = \( \frac{1}{2} (10 - 6) = 2 \). - For N₂²⁻: - Bonding electrons: 10 (same as O₂) - Antibonding electrons: 4 (σ*1s² + σ*2s²) - Bond order = \( \frac{1}{2} (10 - 4) = 3 \). 4. **Conclusion**: - The assertion is **incorrect** because O₂ and N₂²⁻ do not have the same molecular orbital configuration. - The reasoning is **incorrect** because O₂ has a bond order of 2, while N₂²⁻ has a bond order of 3. - Therefore, both the assertion and reasoning are incorrect. ### Final Answer: Both the assertion and reasoning are incorrect.

To solve the question, we need to analyze the assertion and reasoning provided: **Assertion**: O₂ and N₂²⁻ have the same number of electrons and the same molecular orbital configuration. **Reasoning**: O₂ and N₂²⁻ have the same bond order. ### Step-by-Step Solution: 1. **Determine the Number of Electrons**: ...
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