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Assertion Both NO(3)^(Theta) and CO(3)^(...

Assertion Both `NO_(3)^(Theta)` and `CO_(3)^(2-)` ions are triangular planar
Reasoning Hybridisation of central atom in both `NO_(3)^(Theta)` and `CO_(3)^(2-)` is sp^(2)` .

A

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`

B

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`

C

If `(A)` is correct but `(R )` is incorrect

D

If `(A)` is incorrect but `(R )` is correct

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The correct Answer is:
To solve the question, we need to analyze both the assertion and the reasoning statements provided. ### Step 1: Analyze the Assertion The assertion states that both \( \text{NO}_3^- \) (nitrate ion) and \( \text{CO}_3^{2-} \) (carbonate ion) are trigonal planar. - **Nitrate Ion \( \text{NO}_3^- \)**: - Nitrogen (N) is the central atom, and it is bonded to three oxygen (O) atoms. - The Lewis structure shows that nitrogen forms three bonds with oxygen, and there is one lone pair on nitrogen. - The arrangement of the three oxygen atoms around nitrogen leads to a trigonal planar geometry. - **Carbonate Ion \( \text{CO}_3^{2-} \)**: - Carbon (C) is the central atom, and it is bonded to three oxygen (O) atoms. - The Lewis structure shows that carbon forms one double bond with one oxygen and single bonds with the other two oxygens, with a formal charge distribution that results in a trigonal planar shape. - The arrangement of the three oxygen atoms around carbon also leads to a trigonal planar geometry. Thus, the assertion is **correct**. ### Step 2: Analyze the Reasoning The reasoning states that the hybridization of the central atom in both \( \text{NO}_3^- \) and \( \text{CO}_3^{2-} \) is \( \text{sp}^2 \). - **Hybridization of Nitrogen in \( \text{NO}_3^- \)**: - Nitrogen forms three sigma bonds (one with each oxygen) and has no lone pairs (considering resonance structures). - The hybridization of nitrogen in this case is indeed \( \text{sp}^2 \). - **Hybridization of Carbon in \( \text{CO}_3^{2-} \)**: - Carbon also forms three sigma bonds (one with each oxygen). - The hybridization of carbon in this case is also \( \text{sp}^2 \). Thus, the reasoning is also **correct**. ### Conclusion Both the assertion and reasoning are correct, and the reasoning correctly explains the assertion. ### Final Answer Both statements are correct, and the second statement is the correct explanation for the first.

To solve the question, we need to analyze both the assertion and the reasoning statements provided. ### Step 1: Analyze the Assertion The assertion states that both \( \text{NO}_3^- \) (nitrate ion) and \( \text{CO}_3^{2-} \) (carbonate ion) are trigonal planar. - **Nitrate Ion \( \text{NO}_3^- \)**: - Nitrogen (N) is the central atom, and it is bonded to three oxygen (O) atoms. - The Lewis structure shows that nitrogen forms three bonds with oxygen, and there is one lone pair on nitrogen. ...
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