Home
Class 11
CHEMISTRY
Assertion Boiling point of halogen acids...

Assertion Boiling point of halogen acids are in the order `HF gtHBr gt HCl gt HI`
Reasoning Electronegativities are in the order `F gt Cl gt Br gt I` .

A

If both `(A)` and `(R )` are correct and `(R )` is the correct
explanation of `(A)`

B

If both `(A)` and `(R )` are correct and `(R )` is the correct
explanation of `(A)`

C

If `(A)` is correct but `(R )` is incorrect

D

If `(A)` is incorrect but `(R )` is correct

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion and reasoning question regarding the boiling points of halogen acids and their electronegativities, we can follow these steps: ### Step 1: Understand the Assertion The assertion states that the boiling points of halogen acids are in the order \( HF > HBr > HCl > HI \). We need to evaluate if this order is correct. ### Step 2: Analyze the Reasoning The reasoning provided states that the electronegativities of the halogens are in the order \( F > Cl > Br > I \). We need to confirm if this order is accurate. ### Step 3: Evaluate the Reasoning The reasoning is based on the trend of electronegativity in Group 17 (the halogens). As we move down the group from fluorine to iodine, the size of the atoms increases, which leads to a decrease in electronegativity. This statement is correct. ### Step 4: Evaluate the Assertion Now, let's analyze the boiling points of the halogen acids: - **HF**: Has the highest boiling point due to strong intermolecular hydrogen bonding. - **HCl, HBr, HI**: These do not exhibit hydrogen bonding. Instead, their boiling points are influenced by Van der Waals forces, which increase with molecular size. As we move down the group: - **HCl** has a lower boiling point than **HBr** and **HI** because it is smaller in size compared to **HBr** and **HI**. - **HI** has the highest boiling point among HCl, HBr, and HI due to its larger size leading to stronger Van der Waals forces. Thus, the correct order of boiling points should be: \[ HF > HI > HBr > HCl \] ### Step 5: Conclusion The assertion that the boiling points of halogen acids are in the order \( HF > HBr > HCl > HI \) is incorrect. However, the reasoning regarding electronegativities is correct. ### Final Answer - **Assertion**: Incorrect - **Reasoning**: Correct

To solve the assertion and reasoning question regarding the boiling points of halogen acids and their electronegativities, we can follow these steps: ### Step 1: Understand the Assertion The assertion states that the boiling points of halogen acids are in the order \( HF > HBr > HCl > HI \). We need to evaluate if this order is correct. ### Step 2: Analyze the Reasoning The reasoning provided states that the electronegativities of the halogens are in the order \( F > Cl > Br > I \). We need to confirm if this order is accurate. ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer|10 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Fill In The Blanks|20 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct (Miscellaneous)|23 Videos
  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Concept Applicationexercise(4.3)|19 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective type|1 Videos

Similar Questions

Explore conceptually related problems

Assertion( A) The boiling points of alkyl halides decrease in the order RI gt RBr gt RCl gt RF Reason (R) The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass.

The reactivity of carbanions follows the order 3^@ gt 2^@ gt 1^@ .

In group 14 of the periodic table, the oxidising power of tetravalent species decreases in the order a. Ge gt Pb gt Sn b. Ge gt Sn gt Pb c. Pb gt Ge gt Sn d. Pb gt Sn gt Ge

Statement-I: Boiling point of alkyl halide increases with increases in molecular weight. Because Statement-II: Boiling point of alkyhalides are in the order RI gt RBr gt RCI gt RF .

Assertion Boiling point of SiH_(4) gt CH_(4) whereas boiling point of SiCI_(4) lt CCI_(4) Reasoning Chlorine possesses vacant d-orbitals but hydrogen does not .

Account for the following: (i) In reaction involving cleavage of carbon-oxygen bond of alcohols some acid is added to facilitate the reaction. (ii) The order of reactivity of halogen acids with alcohols is HI gt HBr gt HCl . (iii) Phenols do not undergo substitution at the carbon of C-OH bond.

The elevation of boiling point produced by dilute equimolal solutions of three substances are in the order A gt glucose gt B Suggest a reason for this observation.

For hydrogen atom , the energies of the sub-shells 4s ,4p, 4d and 4f are in the order 4f gt 4d gt 4p gt 4s

Assertion : In the coagulation of a negative sol the flocculating power is in the order : Al^(3+) gt Ba^(2+) gt Na^(+) Reason : Greater the valence of the flocculating ion added, greater is its power to cause precipitation.

Assertion:Nuclear binding energy per nucleon is in the order - ""_(4)^9Be gt ""_(3)^(7)Li gt ""_(2)^(4)He . Reason:Binding energy per nucleon increases linearly with difference in number of neutrons and protons.

CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises Assetion Reasoning
  1. Assertion Carbon tetrachloride dose not form a precipitate of AgCI wit...

    Text Solution

    |

  2. Assertion Both NO(3)^(Theta) and CO(3)^(2-) ions are triangular planar...

    Text Solution

    |

  3. Water has maximum density at 4°C.

    Text Solution

    |

  4. Assertion Boiling point of halogen acids are in the order HF gtHBr gt ...

    Text Solution

    |

  5. Assertion Ionic compounds tend to be non-volatile Reasoning Intermol...

    Text Solution

    |

  6. Assertion : Water is a good solvent for ionic compounds but poor for c...

    Text Solution

    |

  7. Assertion : The atoms in a covalent molecule are said to share electro...

    Text Solution

    |

  8. Assertion : Na(2)SO(4) is soluble in water while BaSO(4) is water inso...

    Text Solution

    |

  9. Assertion : The dipole moment helps to predict whether a molecule is ...

    Text Solution

    |

  10. Assertion BF(3) is a weaker Lewis acid than BCI(3) Reasoning In BF(3...

    Text Solution

    |

  11. Assertion Bond order for N(2)^(o+) and N(2)^(Theta) are same (i.e2.5) ...

    Text Solution

    |

  12. Assertion Among two cations of similar size the polarising power of ca...

    Text Solution

    |

  13. Assertion BF(3) has greater dipole momnet than H(2)S Reasoning Fluor...

    Text Solution

    |

  14. Assertion Both pi(2P(x)) and pi^(**)(2P(x))MO's have one nodal plane e...

    Text Solution

    |

  15. Assertion H(2),Li(2),B(2) each has a bond order of 1 and hence are equ...

    Text Solution

    |

  16. Assertion : Bond order can assume any value including zero. Reason :...

    Text Solution

    |

  17. Assertion : N(2) and NO^(+) both are diamagnetic substances. Reason ...

    Text Solution

    |

  18. Assertion B(2) molecule is diamagnetic Reasoning The highest occupie...

    Text Solution

    |

  19. Asseration: SeCl(4), does not havea tetrahedral structure. Reason: S...

    Text Solution

    |

  20. Assertion : All F - S - F angle in SF(4) are greater than 90^(@) but ...

    Text Solution

    |