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Acidic strength order HCIO gtHBrO gtHIO ...

Acidic strength order `HCIO gtHBrO gtHIO` .

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To determine the order of acidic strength of hypohalous acids \( HClO \), \( HBrO \), and \( HI \), we need to analyze the stability of their corresponding anions \( OCl^- \), \( OBr^- \), and \( OI^- \). The stability of these anions will help us understand the acidic strength of the acids. ### Step-by-Step Solution: 1. **Identify the Hypohalous Acids**: - The acids in question are \( HClO \) (hypochlorous acid), \( HBrO \) (hypobromous acid), and \( HI \) (hypoiodous acid). 2. **Dissociation of Acids**: - Each acid dissociates in water to release \( H^+ \) ions and their respective anions: - \( HClO \rightarrow H^+ + OCl^- \) - \( HBrO \rightarrow H^+ + OBr^- \) - \( HI \rightarrow H^+ + OI^- \) 3. **Analyze Stability of Anions**: - The stability of the anions \( OCl^- \), \( OBr^- \), and \( OI^- \) is crucial for determining the acidic strength. - The stability of anions is influenced by the electronegativity of the atom bonded to oxygen. Higher electronegativity leads to better charge distribution and greater stability of the anion. 4. **Electronegativity Order**: - The electronegativity of the halogens decreases as follows: \( Cl > Br > I \). - This means \( OCl^- \) will be more stable than \( OBr^- \), and \( OBr^- \) will be more stable than \( OI^- \). 5. **Conclusion on Acidic Strength**: - Since \( OCl^- \) is the most stable anion, \( HClO \) is the strongest acid. - Next, \( OBr^- \) is less stable than \( OCl^- \), making \( HBrO \) the second strongest acid. - Finally, \( OI^- \) is the least stable, making \( HI \) the weakest acid. - Therefore, the order of acidic strength is \( HClO > HBrO > HI \). ### Final Order: The order of acidic strength is: \[ HClO > HBrO > HI \]

To determine the order of acidic strength of hypohalous acids \( HClO \), \( HBrO \), and \( HI \), we need to analyze the stability of their corresponding anions \( OCl^- \), \( OBr^- \), and \( OI^- \). The stability of these anions will help us understand the acidic strength of the acids. ### Step-by-Step Solution: 1. **Identify the Hypohalous Acids**: - The acids in question are \( HClO \) (hypochlorous acid), \( HBrO \) (hypobromous acid), and \( HI \) (hypoiodous acid). 2. **Dissociation of Acids**: ...
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises True/False
  1. Acidic strength order CI(2)O(7) gtSO(3) gtP(4) O(10) .

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  2. Acidic strength order HCIO gtHBrO gtHIO .

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  3. Basic strength order NH(3) gtPH(3) gtAsH(3) gtBiH(3) .

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  4. XeO(3) is a trigonal pyramidal molecule .

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  5. The lanthanoid ions other than the f^(0) type and f^(14) types are all...

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  6. LiHCO(3) and Ca(HCO(3))(2) are not found in solid state .

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  7. All molecules with polar bonds have dipole moment.

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  8. Assertion : Ionic bonds are directional in nature whereas covalent bo...

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  9. The dipole moment of CH3F is greater than that of CH3Cl.

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  10. The presence of polar bonds in a polyatomic molecule suggests that the...

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  11. The boiling point of HCI is less than that of HF .

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  12. Both PH(3) and PH(5) exist .

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  13. sigma2s, pi^(**) (2p(x)) and pi(2p(x)) are gerade MO .

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  14. Out of NO,NO^(o+) and CN^(o+) the paramagnetic species is NO^(o+) .

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  15. Arrange the following types of intermolecular forces in order of decre...

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  16. sigma2s, pi^(**) (2p(x)) and pi(2p(x)) are gerade MO .

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  17. Predict the order of decreasing boiling points of the following H(2),H...

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  18. (a)Give the decreasing order of melting points of the following NH(3),...

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  19. Out of CH(3)OH and (CH(3))(3)N both exhibit H-bonding .

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  20. CO(2) and N(3)^(Theta) have sane bond order and same shape .

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