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Out of NO,NO^(o+) and CN^(o+) the parama...

Out of `NO,NO^(o+)` and `CN^(o+)` the paramagnetic species is `NO^(o+)` .

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To determine whether the statement is correct, we need to analyze the magnetic properties of the species NO, NO⁺, and CN⁺. A species is considered paramagnetic if it has unpaired electrons in its molecular orbital configuration. ### Step 1: Determine the electron configuration of NO - **Nitric Oxide (NO)** has a total of 11 electrons (7 from nitrogen and 8 from oxygen). - The molecular orbital configuration for NO is: - σ(1s)² σ*(1s)² σ(2s)² σ*(2s)² σ(2p_z)² π(2p_x)¹ π(2p_y)¹ - In this configuration, we can see that there are 2 unpaired electrons in the π(2p_x) and π(2p_y) orbitals. ### Step 2: Determine the electron configuration of NO⁺ - **NO⁺** has one less electron than NO, giving it a total of 10 electrons. - The molecular orbital configuration for NO⁺ is: - σ(1s)² σ*(1s)² σ(2s)² σ*(2s)² σ(2p_z)² π(2p_x)¹ - In this configuration, there is 1 unpaired electron in the π(2p_x) orbital. ### Step 3: Determine the electron configuration of CN⁺ - **Cyanide (CN⁺)** has a total of 10 electrons (6 from carbon and 4 from nitrogen). - The molecular orbital configuration for CN⁺ is: - σ(1s)² σ*(1s)² σ(2s)² σ*(2s)² σ(2p_z)² - In this configuration, all electrons are paired, meaning there are no unpaired electrons. ### Step 4: Analyze the paramagnetic properties - **NO** has 2 unpaired electrons, making it paramagnetic. - **NO⁺** has 1 unpaired electron, making it paramagnetic as well. - **CN⁺** has no unpaired electrons, making it diamagnetic. ### Conclusion The statement that "the paramagnetic species is NO⁺" is correct. Therefore, the correct answer is that both NO and NO⁺ are paramagnetic, while CN⁺ is not.

To determine whether the statement is correct, we need to analyze the magnetic properties of the species NO, NO⁺, and CN⁺. A species is considered paramagnetic if it has unpaired electrons in its molecular orbital configuration. ### Step 1: Determine the electron configuration of NO - **Nitric Oxide (NO)** has a total of 11 electrons (7 from nitrogen and 8 from oxygen). - The molecular orbital configuration for NO is: - σ(1s)² σ*(1s)² σ(2s)² σ*(2s)² σ(2p_z)² π(2p_x)¹ π(2p_y)¹ - In this configuration, we can see that there are 2 unpaired electrons in the π(2p_x) and π(2p_y) orbitals. ...
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises True/False
  1. Acidic strength order CI(2)O(7) gtSO(3) gtP(4) O(10) .

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  2. Acidic strength order HCIO gtHBrO gtHIO .

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  3. Basic strength order NH(3) gtPH(3) gtAsH(3) gtBiH(3) .

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  4. XeO(3) is a trigonal pyramidal molecule .

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  5. The lanthanoid ions other than the f^(0) type and f^(14) types are all...

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  6. LiHCO(3) and Ca(HCO(3))(2) are not found in solid state .

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  7. All molecules with polar bonds have dipole moment.

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  8. Assertion : Ionic bonds are directional in nature whereas covalent bo...

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  9. The dipole moment of CH3F is greater than that of CH3Cl.

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  10. The presence of polar bonds in a polyatomic molecule suggests that the...

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  11. The boiling point of HCI is less than that of HF .

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  12. Both PH(3) and PH(5) exist .

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  13. sigma2s, pi^(**) (2p(x)) and pi(2p(x)) are gerade MO .

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  14. Out of NO,NO^(o+) and CN^(o+) the paramagnetic species is NO^(o+) .

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  15. Arrange the following types of intermolecular forces in order of decre...

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  16. sigma2s, pi^(**) (2p(x)) and pi(2p(x)) are gerade MO .

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  17. Predict the order of decreasing boiling points of the following H(2),H...

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  18. (a)Give the decreasing order of melting points of the following NH(3),...

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  19. Out of CH(3)OH and (CH(3))(3)N both exhibit H-bonding .

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  20. CO(2) and N(3)^(Theta) have sane bond order and same shape .

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