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B(2)H(6) and B(4)H(10) respectively are ...

`B_(2)H_(6)` and `B_(4)H_(10)` respectively are examples of.

A

Nido and arachno boranes

B

Nido and clso boranes

C

Closo and arachno boranes

D

Nido boranes

Text Solution

AI Generated Solution

The correct Answer is:
To determine what \( B_2H_6 \) and \( B_4H_{10} \) are examples of, we need to classify these boron hydrides based on their structures. Here's a step-by-step solution: ### Step 1: Understand the Types of Boron Hydrides Boron hydrides can be classified into three main categories: 1. **Closo-boranes**: These have a closed structure and follow the general formula \( B_nH_n^{2-} \). 2. **Nido-boranes**: These have an open structure with one vertex missing, and they follow the general formula \( B_nH_n^{+4} \). 3. **Arachno-boranes**: These have an even more open structure with two vertices missing, following the general formula \( B_nH_n^{+6} \). ### Step 2: Analyze \( B_2H_6 \) To classify \( B_2H_6 \): - We can use the general formula for nido-boranes, which is \( B_nH_n^{+4} \). - For \( B_2H_6 \): - Here, \( n = 2 \). - Plugging into the nido formula: \( B_2H_{2+4} = B_2H_6 \). - This confirms that \( B_2H_6 \) is a **nido-borane**. ### Step 3: Analyze \( B_4H_{10} \) Now, let's classify \( B_4H_{10} \): - We can use the general formula for arachno-boranes, which is \( B_nH_n^{+6} \). - For \( B_4H_{10} \): - Here, \( n = 4 \). - Plugging into the arachno formula: \( B_4H_{4+6} = B_4H_{10} \). - This confirms that \( B_4H_{10} \) is an **arachno-borane**. ### Conclusion Thus, \( B_2H_6 \) and \( B_4H_{10} \) are respectively examples of **nido-boranes** and **arachno-boranes**. ### Final Answer **\( B_2H_6 \) is a nido-borane and \( B_4H_{10} \) is an arachno-borane.** ---
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