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"Colemanite" + Na(2)CO(3) overset("Fused...

`"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2)`
`underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3)`
`(B) + conc HCl rarr NaCl + underset("Acid")((C))`
`underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D))`
`(D) overset("Strong heating")rarr (E)`
`(E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F))`.
Colemanite is.

A

`Ca_(2)B_(2)O_(11)`

B

`Ca_(2)B_(6)O_(11)`

C

`Ca_(4)B_(4)O_(11)`

D

`Ca_(6)B_(6)O_(11)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reactions involving "Colemanite," we will analyze each step of the reaction sequence and identify the compounds involved. 1. **Identifying Colemanite**: Colemanite is a borate mineral with the chemical formula \( \text{Ca}_2\text{B}_6\text{O}_{11} \cdot 5\text{H}_2\text{O} \). It is primarily composed of calcium, boron, and oxygen. 2. **First Reaction**: The first reaction involves Colemanite reacting with sodium carbonate (\( \text{Na}_2\text{CO}_3 \)) when fused. The products of this reaction are: - (A) Sodium borate, which can be represented as \( \text{Na}_2\text{B}_4\text{O}_7 \) (borax). - (B) Calcium carbonate (\( \text{CaCO}_3 \)). - Carbon dioxide (\( \text{CO}_2 \)) is also produced. Thus, the first reaction can be summarized as: \[ \text{Ca}_2\text{B}_6\text{O}_{11} \cdot 5\text{H}_2\text{O} + \text{Na}_2\text{CO}_3 \xrightarrow{\text{Fused}} \text{Na}_2\text{B}_4\text{O}_7 + \text{CaCO}_3 + \text{CO}_2 \] 3. **Second Reaction**: The sodium borate (A) reacts with carbon dioxide to regenerate sodium carbonate (B): \[ \text{Na}_2\text{B}_4\text{O}_7 + \text{CO}_2 \rightarrow \text{B} + \text{Na}_2\text{CO}_3 \] 4. **Third Reaction**: The compound (B) reacts with concentrated hydrochloric acid (\( \text{HCl} \)): \[ \text{CaCO}_3 + \text{conc HCl} \rightarrow \text{NaCl} + \text{C} \] Here, (C) is calcium chloride (\( \text{CaCl}_2 \)). 5. **Fourth Reaction**: The acid (C) reacts with water: \[ \text{CaCl}_2 + \text{H}_2\text{O} \rightarrow \text{D} \] (D) is calcium hydroxide (\( \text{Ca(OH)}_2 \)). 6. **Fifth Reaction**: The compound (D) undergoes strong heating: \[ \text{Ca(OH)}_2 \xrightarrow{\text{Strong heating}} \text{E} \] (E) is calcium oxide (\( \text{CaO} \)). 7. **Sixth Reaction**: Finally, calcium oxide (E) reacts with copper sulfate (\( \text{CuSO}_4 \)) when heated: \[ \text{CaO} + \text{CuSO}_4 \xrightarrow{\text{Heated}} \text{F} \] (F) is the blue-colored compound, which is copper(II) oxide (\( \text{CuO} \)). ### Summary of Compounds: - (A) Sodium borate: \( \text{Na}_2\text{B}_4\text{O}_7 \) - (B) Calcium carbonate: \( \text{CaCO}_3 \) - (C) Calcium chloride: \( \text{CaCl}_2 \) - (D) Calcium hydroxide: \( \text{Ca(OH)}_2 \) - (E) Calcium oxide: \( \text{CaO} \) - (F) Copper(II) oxide: \( \text{CuO} \) ### Final Answer: Colemanite is \( \text{Ca}_2\text{B}_6\text{O}_{11} \cdot 5\text{H}_2\text{O} \).

To solve the question regarding the reactions involving "Colemanite," we will analyze each step of the reaction sequence and identify the compounds involved. 1. **Identifying Colemanite**: Colemanite is a borate mineral with the chemical formula \( \text{Ca}_2\text{B}_6\text{O}_{11} \cdot 5\text{H}_2\text{O} \). It is primarily composed of calcium, boron, and oxygen. 2. **First Reaction**: The first reaction involves Colemanite reacting with sodium carbonate (\( \text{Na}_2\text{CO}_3 \)) when fused. The products of this reaction are: - (A) Sodium borate, which can be represented as \( \text{Na}_2\text{B}_4\text{O}_7 \) (borax). ...
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"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (E) is.

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (D) is.

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (B) is.

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (F) is.

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (C) is.

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (A) is.

SiCl_(4)overset(H_(2)O)rarr(A)overset("Heat")rarr (B) overset(Na_(2)CO_(3))underset("Heat")rarr(C ) , The compound (C ) is

underset(("Sulphide ore")) (A) + NaCN overset ("Air") hArr underset(("Complex"))(B) +Na_(2) S overset(O_(2))rarr C . B is.

underset(("Sulphide ore")) (A) + NaCN overset ("Air") hArr underset(("Complex"))(B) +Na_(2) S overset(O_(2))rarr C . C is.

underset(("Sulphide ore")) (A) + NaCN overset ("Air") hArr underset(("Complex"))(B) +Na_(2) S overset(O_(2))rarr C . A is.

CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 13 - BORON FAMILY-Exercise (Linked Comprehension)
  1. Despite the fact that aluminium is a reactive metal, it is a stable in...

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  2. Despite the fact that aluminium is a reactive metal, it is a stable in...

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  3. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  4. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  5. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  6. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  7. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  8. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  9. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  10. Boron with hydrogen forms a number of hydrides which are known are b...

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  11. Boron with hydrogen forms a number of hydrides which are known are bor...

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  12. Boron with hydrogen forms a number of hydrides which are known are b...

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  13. Boron with hydrogen forms a number of hydrides which are known are bor...

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  14. Boron with hydrogen forms a number of hydrides which are known are b...

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  15. Boron with hydrogen forms a number of hydrides which are known are bor...

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  16. Boron with hydrogen forms a number of hydrides which are known are b...

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  17. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  18. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts ...

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  19. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  20. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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