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"Colemanite" + Na(2)CO(3) overset("Fused...

`"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2)`
`underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3)`
`(B) + conc HCl rarr NaCl + underset("Acid")((C))`
`underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D))`
`(D) overset("Strong heating")rarr (E)`
`(E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F))`.
Compound `(D)` is.

A

`H_(2)B_(4)O_(7)`

B

`HBO_(2)`

C

`H_(3)BO_(3)`

D

`H_(2)O`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will follow the reactions provided and identify compound (D). ### Step 1: Reaction of Colemanite with Sodium Carbonate **Reaction:** \[ \text{Colemanite (Ca}_2\text{B}_6\text{O}_{11}) + \text{Na}_2\text{CO}_3 \xrightarrow{\text{Fused}} (A) + (B) + \text{CO}_2 \] **Products:** - (A) = Sodium Metaborate \((\text{NaBO}_2)\) - (B) = Sodium Tetraborate \((\text{Na}_2\text{B}_4\text{O}_7)\) - \(\text{CO}_2\) is also produced. ### Step 2: Reaction of (A) with CO2 **Reaction:** \[ (A) + \text{CO}_2 \rightarrow (B) + \text{Na}_2\text{CO}_3 \] **Products:** - (B) = Sodium Tetraborate \((\text{Na}_2\text{B}_4\text{O}_7)\) ### Step 3: Reaction of (B) with Concentrated HCl **Reaction:** \[ (B) + \text{conc HCl} \rightarrow \text{NaCl} + (C) \] **Products:** - (C) = Tetraboric Acid \((\text{H}_2\text{B}_4\text{O}_7)\) ### Step 4: Reaction of (C) with Water **Reaction:** \[ (C) + \text{H}_2\text{O} \rightarrow (D) \] **Products:** - (D) = Boric Acid \((\text{H}_3\text{BO}_3)\) ### Step 5: Strong Heating of (D) **Reaction:** \[ (D) \xrightarrow{\text{Strong heating}} (E) \] **Products:** - (E) = A product that can further react with CuSO4. ### Step 6: Reaction of (E) with CuSO4 **Reaction:** \[ (E) + \text{CuSO}_4 \xrightarrow{\text{Heated}} (F) \] **Products:** - (F) = Blue-coloured compound (likely a copper borate). ### Conclusion The compound (D) is **Boric Acid** \((\text{H}_3\text{BO}_3)\). ---

To solve the problem step by step, we will follow the reactions provided and identify compound (D). ### Step 1: Reaction of Colemanite with Sodium Carbonate **Reaction:** \[ \text{Colemanite (Ca}_2\text{B}_6\text{O}_{11}) + \text{Na}_2\text{CO}_3 \xrightarrow{\text{Fused}} (A) + (B) + \text{CO}_2 \] **Products:** - (A) = Sodium Metaborate \((\text{NaBO}_2)\) ...
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"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Colemanite is.

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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 13 - BORON FAMILY-Exercise (Linked Comprehension)
  1. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  2. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  3. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  4. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  5. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  6. Boron with hydrogen forms a number of hydrides which are known are b...

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  7. Boron with hydrogen forms a number of hydrides which are known are bor...

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  8. Boron with hydrogen forms a number of hydrides which are known are b...

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  9. Boron with hydrogen forms a number of hydrides which are known are bor...

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  10. Boron with hydrogen forms a number of hydrides which are known are b...

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  11. Boron with hydrogen forms a number of hydrides which are known are bor...

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  12. Boron with hydrogen forms a number of hydrides which are known are b...

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  13. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  14. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts ...

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  15. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  16. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  17. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  18. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  19. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts ...

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  20. Read the following structural aspects of borax and answer the question...

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