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"Colemanite" + Na(2)CO(3) overset("Fused...

`"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2)`
`underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3)`
`(B) + conc HCl rarr NaCl + underset("Acid")((C))`
`underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D))`
`(D) overset("Strong heating")rarr (E)`
`(E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F))`.
Compound `(E)` is.

A

`B_(2)O_(3)`

B

`B`

C

`H_(3)BO_(3)`

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question step by step, we will analyze the reactions provided and identify the compounds A, B, C, D, and E sequentially. ### Step 1: Identify Compound A The first reaction involves Colemanite (Ca2B6O11) reacting with sodium carbonate (Na2CO3) upon fusion. The products of this reaction are: - A: Sodium metaborate (NaBO2) - B: Sodium tetraborate (Na2B4O7) - CO2 Thus, we can write: \[ \text{Colemanite} + \text{Na}_2\text{CO}_3 \xrightarrow{\text{Fused}} \text{NaBO}_2 \, (A) + \text{Na}_2\text{B}_4\text{O}_7 \, (B) + \text{CO}_2 \] ### Step 2: Identify Compound B Next, we take compound A (NaBO2) and react it with carbon dioxide (CO2). The products of this reaction are: - B: Sodium tetraborate (Na2B4O7) - Na2CO3 So, we can express this reaction as: \[ \text{NaBO}_2 \, (A) + \text{CO}_2 \rightarrow \text{Na}_2\text{B}_4\text{O}_7 \, (B) + \text{Na}_2\text{CO}_3 \] ### Step 3: Identify Compound C Now, we take compound B (Na2B4O7) and react it with concentrated hydrochloric acid (HCl). The products of this reaction are: - NaCl - C: Boric acid (H3BO3) Thus, we have: \[ \text{Na}_2\text{B}_4\text{O}_7 \, (B) + \text{conc HCl} \rightarrow \text{NaCl} + \text{H}_2\text{B}_4\text{O}_7 \, (C) \] ### Step 4: Identify Compound D Next, we take compound C (H2B4O7) and react it with water (H2O). The product of this reaction is: - D: Boric acid (H3BO3) This can be represented as: \[ \text{H}_2\text{B}_4\text{O}_7 \, (C) + \text{H}_2\text{O} \rightarrow \text{H}_3\text{BO}_3 \, (D) \] ### Step 5: Identify Compound E Finally, we take compound D (H3BO3) and subject it to strong heating. The product of this reaction is: - E: Boron trioxide (B2O3) This can be expressed as: \[ 2 \text{H}_3\text{BO}_3 \, (D) \xrightarrow{\text{Strong heating}} \text{B}_2\text{O}_3 \, (E) + 3 \text{H}_2\text{O} \] ### Conclusion Thus, the compound E is: \[ \text{B}_2\text{O}_3 \]

To solve the question step by step, we will analyze the reactions provided and identify the compounds A, B, C, D, and E sequentially. ### Step 1: Identify Compound A The first reaction involves Colemanite (Ca2B6O11) reacting with sodium carbonate (Na2CO3) upon fusion. The products of this reaction are: - A: Sodium metaborate (NaBO2) - B: Sodium tetraborate (Na2B4O7) - CO2 ...
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 13 - BORON FAMILY-Exercise (Linked Comprehension)
  1. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  2. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  3. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  4. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  5. Boron with hydrogen forms a number of hydrides which are known are b...

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  6. Boron with hydrogen forms a number of hydrides which are known are bor...

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  7. Boron with hydrogen forms a number of hydrides which are known are b...

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  8. Boron with hydrogen forms a number of hydrides which are known are bor...

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  9. Boron with hydrogen forms a number of hydrides which are known are b...

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  10. Boron with hydrogen forms a number of hydrides which are known are bor...

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  11. Boron with hydrogen forms a number of hydrides which are known are b...

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  12. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  13. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts ...

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  14. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  15. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  16. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  17. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  18. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts ...

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  19. Read the following structural aspects of borax and answer the question...

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  20. Read the following structural aspects of borax and answer the question...

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