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"Colemanite" + Na(2)CO(3) overset("Fused...

`"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2)`
`underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3)`
`(B) + conc HCl rarr NaCl + underset("Acid")((C))`
`underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D))`
`(D) overset("Strong heating")rarr (E)`
`(E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F))`.
Compound `(F)` is.

A

`CuS`

B

`Cu_(2)O`

C

`CuSO_(3)`

D

`Cu(BO_(2))_(3)`

Text Solution

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The correct Answer is:
To solve the question step by step, we will analyze the reactions and identify the compounds involved. ### Step 1: Reaction of Colemanite with Sodium Carbonate The first reaction involves Colemanite (Ca2B6O11) reacting with sodium carbonate (Na2CO3) when fused. The products formed are: - (A): Sodium Metaborate (NaBO2) - (B): Sodium Tetraborate (Na2B4O7) - Byproduct: Carbon Dioxide (CO2) **Products:** - A = NaBO2 - B = Na2B4O7 - CO2 is also produced. ### Step 2: Reaction of A with CO2 Next, sodium metaborate (A) reacts with carbon dioxide (CO2) to form: - (B): Sodium Tetraborate (Na2B4O7) - Byproduct: Sodium Carbonate (Na2CO3) **Products:** - A + CO2 → B + Na2CO3 ### Step 3: Reaction of B with Concentrated HCl Now, sodium tetraborate (B) reacts with concentrated hydrochloric acid (HCl) to produce: - Sodium Chloride (NaCl) - (C): Tetraboric Acid (H2B4O7) **Products:** - B + HCl → NaCl + C (where C = H2B4O7) ### Step 4: Reaction of C with Water The tetraboric acid (C) then reacts with water (H2O) to yield: - (D): Tetraboric Acid remains the same (H2B4O7) **Products:** - C + H2O → D (where D = H2B4O7) ### Step 5: Strong Heating of D Upon strong heating of (D), we get: - (E): Boron Trioxide (B2O3) - Byproduct: Water (H2O) **Products:** - D (H2B4O7) → E (B2O3) + H2O ### Step 6: Reaction of E with Copper Sulfate Finally, boron trioxide (E) reacts with copper sulfate (CuSO4) when heated in a flame to produce: - (F): Copper(II) Borate (CuB2O4), which is a blue-colored compound. **Products:** - E + CuSO4 → F (where F = CuB2O4) ### Conclusion The blue-colored compound (F) formed in the last reaction is **Copper(II) Borate (CuB2O4)**. ---

To solve the question step by step, we will analyze the reactions and identify the compounds involved. ### Step 1: Reaction of Colemanite with Sodium Carbonate The first reaction involves Colemanite (Ca2B6O11) reacting with sodium carbonate (Na2CO3) when fused. The products formed are: - (A): Sodium Metaborate (NaBO2) - (B): Sodium Tetraborate (Na2B4O7) - Byproduct: Carbon Dioxide (CO2) ...
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"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Colemanite is.

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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 13 - BORON FAMILY-Exercise (Linked Comprehension)
  1. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  2. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  3. "Colemanite" + Na(2)CO(3) overset("Fused")rarr (A) + (B) + CO(2) und...

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  4. Boron with hydrogen forms a number of hydrides which are known are b...

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  5. Boron with hydrogen forms a number of hydrides which are known are bor...

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  6. Boron with hydrogen forms a number of hydrides which are known are b...

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  7. Boron with hydrogen forms a number of hydrides which are known are bor...

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  8. Boron with hydrogen forms a number of hydrides which are known are b...

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  9. Boron with hydrogen forms a number of hydrides which are known are bor...

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  10. Boron with hydrogen forms a number of hydrides which are known are b...

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  11. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  12. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts ...

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  13. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  14. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  15. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  16. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts wi...

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  17. Boron reacts with oxygen at 700^@C to give (A). Compound (A) reacts ...

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  18. Read the following structural aspects of borax and answer the question...

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  19. Read the following structural aspects of borax and answer the question...

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  20. The molecular shapes of diborane is shown below : . Consider the f...

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