Home
Class 11
CHEMISTRY
Why does elemental silicon not form a gr...

Why does elemental silicon not form a graphite-like structure, whereas carbon does?

Text Solution

Verified by Experts

In graphite carbon is `sp^2` hybridese and each carbon forms convalent bonds with three carbon atoms and forms extende hexaogonal rign -Like structure in the layer . Each carbon is now left with one unpaird electron in unhyridsed `2p` orbital which undrgoes sidways ovelap to form `p pi- p pi` double bonds . Thus , graphite has a two-dimensional sheet-like (alyered) stuture .
On the other hand Si is not capable of forming structure like fraphite. Due to its bigger size. exteny of overlap , which cannot form `Si = Si`. Rather. Si prefes to undrgo `sp^3` hdycridisation and hence silicon has a diamond-like three-dimensional netword structure
` (##KSV_INORG_CHM_P1_C07_S01_026_S01.png" width="80%">.
Promotional Banner

Topper's Solved these Questions

  • P-BLOCK GROUP 14 - CARBON FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex (Objective)|19 Videos
  • P-BLOCK GROUP 14 - CARBON FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Linked Comprehension)|31 Videos
  • P-BLOCK GROUP 14 - CARBON FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Examples|9 Videos
  • P-BLOCK GROUP 13 - BORON FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise Archives (Subjecive)|9 Videos
  • PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Archives )Subjective|4 Videos

Similar Questions

Explore conceptually related problems

Why does not sillicon form an analogue of graphite?

Why does a plant wilt?

Why does menstruation occur?

Why does napthalene sublime ?

Why does fluorine not form polyfluorides?

Graphite has a two dimensional sheet-like structure in which each carbon atom is sp^3 hybridized .

In Spirogyra, ladder like structure is formed in

Why does distilled water not conduct electricity, whereas rain water does?

Why does the percentage of gases like oxygen, nitrogen and carbon dioxide remain almost the same in the atmosphere?

Which of the group element does not form M(III) iodide?

CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 14 - CARBON FAMILY-Ex (Subjective)
  1. Explain giving reasons the following: C Cl4 is not hydrolysed with ...

    Text Solution

    |

  2. Why does elemental silicon not form a graphite-like structure, whereas...

    Text Solution

    |

  3. Which of the following elements forms predominantly covalent compounds...

    Text Solution

    |

  4. Cetenation i.e., linking of similar atoms depends on size and electron...

    Text Solution

    |

  5. Give one chemical reaction to show that tin (II) is a reducing agent w...

    Text Solution

    |

  6. Explain, why is CO2 a gas at room temperature but SiO2 is a high melti...

    Text Solution

    |

  7. Give one chemical reaction to show that tin (II) is a reducing agent w...

    Text Solution

    |

  8. Account for the following: C and Si show tetravalency in most of the...

    Text Solution

    |

  9. Tendency to exhibit +2 oxidation state increases with increasing atom...

    Text Solution

    |

  10. Why trimethylamine si pyramidal but trisiluylamine is planar ?

    Text Solution

    |

  11. (CH3)3N acts as a Lewis base , but (SiH3)3 have very little basic char...

    Text Solution

    |

  12. Explain the stability order of CO & SiO & give reason for same .

    Text Solution

    |

  13. PbX2 is more stable than PbX4 (X = CI, Br, I). Account for it.

    Text Solution

    |

  14. Account for the following observations (a) AlCl(3) is a Lewis acid ...

    Text Solution

    |

  15. Give reason : CO is readily absorbed by ammoniacal cuprous chloride,...

    Text Solution

    |

  16. Silanes are few in number whereas alkanes are large in number . Explai...

    Text Solution

    |

  17. Predict whether the following molecules are isostructural or not Justi...

    Text Solution

    |

  18. For a mineral . LiAl (SiO3)2, what is the charge on SiO3 unit ? What...

    Text Solution

    |

  19. A metal M forms two chlorides M Cl2 and MCl4 respectively . In which g...

    Text Solution

    |

  20. An inorganic compound (X) made up of two most occurring elements in ...

    Text Solution

    |