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Which of the following elements forms pr...

Which of the following elements forms predominantly covalent compounds as compared to other elements which form ionic compounds?

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Carbon , due to very high sum of first four ionisation enthalphies , cannot lose all the four valence electrons `( 2p^2 2p^2)` to form `C^(4+)` ion. Carbon cannot gain four eelctrons to form `C^(4+)` ion as this anion would be highly unstalble as it would be vety difficult for a nucleus with only `6` proton to held on firmly `10` electrons , Carbon can only form covalent componds by sharing og elecrons .
On the othe hand in lead , due to inert paire effect `+2` oxidation state is mnore stable as compard to `+4` oxidation state . Down the frop `(narr)`, ionisation enrthalpy decrease. Hence, the sum of first two ioinisation enthalpies of lead is quite low and lead can easily lose two electrons to form `Pb^(2+)` ion . As a result , lead forms ionci compound .
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 14 - CARBON FAMILY-Ex (Subjective)
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  2. Why does elemental silicon not form a graphite-like structure, whereas...

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  6. Explain, why is CO2 a gas at room temperature but SiO2 is a high melti...

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  7. Give one chemical reaction to show that tin (II) is a reducing agent w...

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  8. Account for the following: C and Si show tetravalency in most of the...

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  9. Tendency to exhibit +2 oxidation state increases with increasing atom...

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  10. Why trimethylamine si pyramidal but trisiluylamine is planar ?

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  12. Explain the stability order of CO & SiO & give reason for same .

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  13. PbX2 is more stable than PbX4 (X = CI, Br, I). Account for it.

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  15. Give reason : CO is readily absorbed by ammoniacal cuprous chloride,...

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  16. Silanes are few in number whereas alkanes are large in number . Explai...

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  17. Predict whether the following molecules are isostructural or not Justi...

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  18. For a mineral . LiAl (SiO3)2, what is the charge on SiO3 unit ? What...

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