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The incorrect statement (s0 among the fo...

The incorrect statement (s0 among the following is //are :

A

`Nci_5` does not exist buyt `PCl_5` does

B

Lead prefers to form tetravalent compounds

C

The three `C-O` bonds are not equal in the `CO_3^(2-)` ion.

D

Both ` O_2^(o+)` and `NO` are paramagnetic .

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the incorrect statements among the provided options, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Evaluate Statement A: "nCl5 does not exist but PCl5 exists."** - **Analysis:** Nitrogen (N) does not have vacant d orbitals, which means it cannot expand its valency beyond four. Therefore, nCl5 cannot exist. On the other hand, phosphorus (P) has vacant d orbitals and can form PCl5. - **Conclusion:** This statement is **true**. 2. **Evaluate Statement B: "Lead prefers to form tetravalent compounds."** - **Analysis:** Lead (Pb) typically forms bivalent compounds (Pb^2+) rather than tetravalent compounds (Pb^4+). The preference for bivalency is due to the inert pair effect, where the s-electrons are less available for bonding in heavier p-block elements. - **Conclusion:** This statement is **false** (incorrect). 3. **Evaluate Statement C: "The three carbon-oxygen bonds are not equal in CO3^2- ion."** - **Analysis:** In the carbonate ion (CO3^2-), the three carbon-oxygen bonds are equivalent due to resonance. The negative charge is delocalized over the three oxygen atoms, leading to equal bond lengths. - **Conclusion:** This statement is **false** (incorrect). 4. **Evaluate Statement D: "Both O2+ and NO are paramagnetic."** - **Analysis:** O2+ has unpaired electrons and is paramagnetic. Similarly, nitric oxide (NO) also has an unpaired electron, making it paramagnetic as well. - **Conclusion:** This statement is **true**. ### Final Answer: The incorrect statements among the options are **B and C**.

To solve the question regarding the incorrect statements among the provided options, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Evaluate Statement A: "nCl5 does not exist but PCl5 exists."** - **Analysis:** Nitrogen (N) does not have vacant d orbitals, which means it cannot expand its valency beyond four. Therefore, nCl5 cannot exist. On the other hand, phosphorus (P) has vacant d orbitals and can form PCl5. - **Conclusion:** This statement is **true**. ...
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