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Assertion (A) : Diamond is the hardest ...

Assertion (A) : Diamond is the hardest possible substance and is a network covalent solid .
Reason (R) : All the `C` atoms in diamond are `sp^2` hybridized .

A

If both (A) and (R) are correct and (R) is correct explanation of (A)

B

If both (A) and (R) are correct and (R) is not correct explanation of (A)

C

If (A) is correct , but (R) is incorrect

D

If (A) is incrorect byt (R) is incroroect .

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Evaluate the Assertion The assertion states: "Diamond is the hardest possible substance and is a network covalent solid." - **Explanation**: Diamond is indeed one of the hardest known natural substances. It is composed of carbon atoms arranged in a tetrahedral lattice structure, where each carbon atom is covalently bonded to four other carbon atoms. This extensive network of strong covalent bonds gives diamond its exceptional hardness. ### Step 2: Evaluate the Reason The reason states: "All the carbon atoms in diamond are sp² hybridized." - **Explanation**: This statement is incorrect. In diamond, the carbon atoms are actually sp³ hybridized. Each carbon atom forms four sigma bonds with four neighboring carbon atoms, resulting in a three-dimensional tetrahedral structure. In contrast, sp² hybridization is found in structures like graphite, where carbon atoms are arranged in planar sheets. ### Step 3: Conclusion Based on the evaluations: - The assertion is **correct**: Diamond is the hardest substance and is a network covalent solid. - The reason is **incorrect**: The carbon atoms in diamond are sp³ hybridized, not sp². Thus, the correct answer is that the assertion is true, but the reason is false. ### Final Answer The assertion is correct, but the reason is incorrect. ---
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 14 - CARBON FAMILY-Exercises (Assertion-Reasoning)
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  2. Assertion (A) : N (SiH3)3 is a weaker based thanN (CH3)3 Reason (R)...

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  3. Assertion (A) : Diamond is the hardest possible substance and is a ne...

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  4. Assertion (A) : Diamond does not reflect light . Reason (R) : Diamo...

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  5. Assertion (A) : C(60) fullerence is an allotrope if carbon. Reason (...

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  6. Assertion: Pb^(4+)can be reduced easily to Pb^(2+). Reason: Pb^(2+) ...

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  7. Assertion (A) : PbI4 is a stable compound . Reason (R) : Iodide ion...

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  8. Assertion: SiF(6)^(2-) is known but SiCl(6)^(2-) is not. Reason: Siz...

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  9. Assertion (A) : Silicones are hdyreopbhobic in nature . Reason (R) ...

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  10. Assertion (A) : SnI4 is an orange solid . Reason (R) : The colur a...

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  11. Assertion (A) : Graphite is a good conductor of heat and electricity ...

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  12. Assertion : Carbon monoxide is a poisonous gas Reason : Carbon monox...

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  13. Assertion (A) : Carbon forms a large number of compounds . Reason ...

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  14. Assertion (A) : Both CO2 snd SiO2 have same structure . Reason (R)...

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  15. Assertion (A) : Lead leaves a black amrek on paore Reason (R) : Le...

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  16. Assertion (A) : CO2 is linear Reason (R) : C is not in sp- hybridi...

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  17. Assertion (A) : Maximum covalency of carbon is four . Reason (R) : ...

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  18. Assertion (A) : Graphite is soft while diamond is very hard . Reaso...

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  19. Assertion (A) : Silica is soluble in HF. Reason (R) : SiO2 + 4HF ...

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  20. Assertion (A) : Graphite is chemically more reactive than diamond . ...

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