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Assertion: Pb^(4+)can be reduced easily ...

Assertion: `Pb^(4+)`can be reduced easily to `Pb^(2+)`.
Reason: `Pb^(2+)` is paramagnetic.

A

If both (A) and (R) are correct and (R) is correct explanation of (A)

B

If both (A) and (R) are correct and (R) is correct explanation of (A)

C

If (A) is correct , but (R) is incorrect

D

If (A) is incrorect byt (R) is incroroect .

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The correct Answer is:
To solve the assertion-reason question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that `Pb^(4+)` can be reduced easily to `Pb^(2+)`. - This reduction is primarily influenced by the inert pair effect, which refers to the tendency of the outermost s-electrons to remain paired and not participate in bonding as we move down the group in the periodic table. 2. **Analyzing the Stability of Oxidation States**: - Lead (Pb) can exist in multiple oxidation states, with `Pb^(4+)` being less stable compared to `Pb^(2+)`. - The `Pb^(2+)` state is more stable due to the inert pair effect, making it easier for `Pb^(4+)` to be reduced to `Pb^(2+)`. 3. **Conclusion on Assertion**: - Since `Pb^(4+)` can indeed be reduced to `Pb^(2+)` easily due to the inert pair effect, the assertion is **correct**. 4. **Understanding the Reason**: - The reason states that `Pb^(2+)` is paramagnetic. - To determine if `Pb^(2+)` is paramagnetic, we need to check its electron configuration and the presence of unpaired electrons. 5. **Electron Configuration of Lead**: - The electron configuration of lead (Pb) is `[Xe] 4f14 5d10 6s2 6p2`. - When lead loses two electrons to form `Pb^(2+)`, it loses the two 6p electrons, resulting in the configuration `[Xe] 4f14 5d10 6s2`. 6. **Determining Magnetic Properties**: - In `Pb^(2+)`, there are no unpaired electrons in the 6s or 6p orbitals, indicating that it is **diamagnetic**. - Since `Pb^(2+)` does not have unpaired electrons, the reason is **incorrect**. 7. **Final Conclusion**: - The assertion is correct, while the reason is incorrect. Therefore, the correct answer is that the assertion is true, but the reason is false. ### Final Answer: - Assertion: True - Reason: False

To solve the assertion-reason question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that `Pb^(4+)` can be reduced easily to `Pb^(2+)`. - This reduction is primarily influenced by the inert pair effect, which refers to the tendency of the outermost s-electrons to remain paired and not participate in bonding as we move down the group in the periodic table. ...
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