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Assertion (A) : Graphite is chemically ...

Assertion (A) : Graphite is chemically more reactive than diamond .
Reason (R) : Diamond is very hard but fraphite si soof .

A

If both (A) and (R) are correct and (R) is correct explanation of (A)

B

If both (A) and (R) are correct and (R) is not correct explanation of (A)

C

If (A) is correct , but (R) is incorrect

D

If (A) is incorrect but (R) is correct .

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The correct Answer is:
To solve the assertion and reason question, we need to analyze both statements carefully. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that "Graphite is chemically more reactive than diamond." - To evaluate this, we need to consider the structure and bonding of both graphite and diamond. 2. **Analyzing Graphite**: - Graphite has a layered structure where carbon atoms are arranged in sheets. - Each carbon atom in graphite is sp² hybridized and is bonded to three other carbon atoms, forming a planar structure. - Importantly, graphite has delocalized π electrons due to the overlapping of p orbitals across the layers, which contributes to its chemical reactivity. 3. **Analyzing Diamond**: - Diamond has a three-dimensional tetrahedral structure where each carbon atom is sp³ hybridized and bonded to four other carbon atoms. - This structure results in strong covalent bonds with no delocalized electrons, making diamond very stable and less reactive compared to graphite. 4. **Conclusion on Assertion**: - Since graphite has delocalized electrons and a structure that allows for chemical reactions, it is indeed more chemically reactive than diamond. Therefore, the assertion is **true**. 5. **Understanding the Reason (R)**: - The reason states that "Diamond is very hard but graphite is soft." - This statement is also correct. Diamond's hardness is due to its strong covalent bonds in a three-dimensional network, while graphite's layered structure allows it to be soft and slippery. 6. **Evaluating the Explanation**: - While both the assertion and the reason are true, the reason does not explain why graphite is more reactive than diamond. The hardness and softness of the materials relate to their structural properties but do not directly account for their chemical reactivity. 7. **Final Conclusion**: - Both the assertion and the reason are correct, but the reason is not the correct explanation for the assertion. Thus, the correct answer is that the assertion is true, and the reason is true but does not explain the assertion. ### Final Answer: - Assertion (A) is true. - Reason (R) is true, but it does not explain (A). - Therefore, the correct option is **B**.

To solve the assertion and reason question, we need to analyze both statements carefully. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that "Graphite is chemically more reactive than diamond." - To evaluate this, we need to consider the structure and bonding of both graphite and diamond. ...
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 14 - CARBON FAMILY-Exercises (Assertion-Reasoning)
  1. Assertion: Pb^(4+)can be reduced easily to Pb^(2+). Reason: Pb^(2+) ...

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  2. Assertion (A) : PbI4 is a stable compound . Reason (R) : Iodide ion...

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  3. Assertion: SiF(6)^(2-) is known but SiCl(6)^(2-) is not. Reason: Siz...

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  4. Assertion (A) : Silicones are hdyreopbhobic in nature . Reason (R) ...

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  5. Assertion (A) : SnI4 is an orange solid . Reason (R) : The colur a...

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  6. Assertion (A) : Graphite is a good conductor of heat and electricity ...

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  7. Assertion : Carbon monoxide is a poisonous gas Reason : Carbon monox...

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  8. Assertion (A) : Carbon forms a large number of compounds . Reason ...

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  9. Assertion (A) : Both CO2 snd SiO2 have same structure . Reason (R)...

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  10. Assertion (A) : Lead leaves a black amrek on paore Reason (R) : Le...

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  11. Assertion (A) : CO2 is linear Reason (R) : C is not in sp- hybridi...

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  12. Assertion (A) : Maximum covalency of carbon is four . Reason (R) : ...

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  13. Assertion (A) : Graphite is soft while diamond is very hard . Reaso...

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  14. Assertion (A) : Silica is soluble in HF. Reason (R) : SiO2 + 4HF ...

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  15. Assertion (A) : Graphite is chemically more reactive than diamond . ...

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  16. Assertion (A) : The compound (CF3)3 N shows almost no basic character...

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  17. Assertion (A) : When CO2 is passed through lime water the solution tu...

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  18. Assertion (A) : SnCl2 has high meling point , whereas snCl4 has low m...

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  19. Assertion (A) : C Cl4 is inert towards hydrolysis but SiCl4 is readi...

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  20. Assertion (A) : Aluminum is passive towares conc HNO3 Reason (R) ...

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