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The soldier of Napolean army while at Al...

The soldier of Napolean army while at Alps during freezing winter suffered a serious problem as regards to the tin buttons of their uniforms. White metallic tin buttons got converted to grey powder. This transformation is related to :

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Due to change in crystal structure of tin.
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The soldiers of Napoleon army while at Alps during freezing winter suffered a serious problem with regard to the tin buttons of their uniform. White metallic tin buttons get converted to grey poweder. This transformation is relate to