Home
Class 12
CHEMISTRY
underset(("Sulphide ore")) (A) + NaCN ov...

`underset(("Sulphide ore")) (A) + NaCN overset ("Air") hArr underset(("Complex"))(B) +Na_(2) S overset(O_(2))rarr C`.
`B` is.

A

Ferromagnetic

B

Paramagnetic

C

Linear complex

D

Coordinate number of central atom is `4`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the complex B formed from the reaction of a sulfide ore with NaCN in the presence of air, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Sulfide Ore (A)**: - The sulfide ore in question can be represented as Ag₂S (Silver Sulfide). 2. **Reaction with Sodium Cyanide (NaCN)**: - When Ag₂S reacts with NaCN in the presence of air, it forms a complex. The reaction can be represented as: \[ \text{Ag}_2\text{S} + 4\text{NaCN} + \text{O}_2 \rightarrow 2\text{Na}_2\text{[Ag(CN)}_2\text{]} + \text{Na}_2\text{S} \] - Here, the complex formed is \(\text{Na}_2\text{[Ag(CN)}_2\text{]}\). 3. **Determine the Nature of Complex B**: - The complex B is \(\text{[Ag(CN)}_2\text{]}^{−}\). - The oxidation state of silver (Ag) in this complex is +1, and it is coordinated with two cyanide (CN) ligands. 4. **Analyze the Magnetic Properties**: - The electronic configuration of Ag in its +1 oxidation state is \([Kr] 4d^{10}\). - Since there are no unpaired electrons in the \(4d^{10}\) configuration, the complex is diamagnetic. 5. **Identify the Coordination Number**: - In the complex \(\text{[Ag(CN)}_2\text{]}\), silver is coordinated to two cyanide ligands, giving it a coordination number of 2. 6. **Conclusion**: - Based on the analysis, complex B is a linear complex with a coordination number of 2 and exhibits diamagnetic properties. ### Answer: B is a **linear complex**.

To solve the question regarding the complex B formed from the reaction of a sulfide ore with NaCN in the presence of air, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Sulfide Ore (A)**: - The sulfide ore in question can be represented as Ag₂S (Silver Sulfide). 2. **Reaction with Sodium Cyanide (NaCN)**: ...
Promotional Banner

Topper's Solved these Questions

  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise (Multiple Correct)|43 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise (Single Correcttype)|106 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exs 1.1 (True Orfalse Statement)|19 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archieves Subjective|35 Videos
  • GRIGNARD REAGENTS AND ORGANOMETALLIC REAGENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Linked Comprehension)|1 Videos

Similar Questions

Explore conceptually related problems

underset(("Sulphide ore")) (A) + NaCN overset ("Air") hArr underset(("Complex"))(B) +Na_(2) S overset(O_(2))rarr C . C is.

underset(("Sulphide ore")) (A) + NaCN overset ("Air") hArr underset(("Complex"))(B) +Na_(2) S overset(O_(2))rarr C . A is.

underset(("Sulphide ore")) (A) + NaCN overset ("Air") hArr underset(("Complex"))(B) +Na_(2) S overset(O_(2))rarr C . Composition of B is.

underset((A))(EtCOCl) overset((i)H_2 N.OH) underset ((ii) overset(Ө)O H) rarr (B) overset(EtOH) rarr (C) Which of the following statements are correct about the given reaction ?

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (B) is.

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (C) is.

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (E) is.

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Colemanite is.

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (D) is.

"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (F) is.