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Metals of high purity are obtained by zo...

Metals of high purity are obtained by zone refining.
Impurities are more soluble in melt in pure metal.

A

If both (A) and ( R) are correct and ( R) is the correct explanation of (A).

B

If both (A) and ( R) are correct, but ( R) is not the correct explanation of (A).

C

If (A) is correct, but ( R) is incorrect.

D

If (A) is incorrect, but ( R) is correct.

Text Solution

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The correct Answer is:
### Step-by-Step Text Solution: 1. **Understanding Zone Refining**: Zone refining is a method used to purify metals. It involves melting a small region (or zone) of a solid metal and then moving this molten zone along the metal rod. 2. **Heating the Metal Rod**: A circular mobile heater is used to heat a specific section of the metal rod. This localized heating causes that section to melt. 3. **Movement of Impurities**: When the metal rod is heated, the impurities present in the solid metal are more soluble in the molten zone than in the solid state. Therefore, as the molten zone forms, the impurities migrate from the solid adjacent areas into the molten zone. 4. **Repetition of the Process**: The circular mobile heater is then moved along the rod, allowing the molten zone to shift. This process is repeated multiple times, causing the impurities to continuously move into the molten zone. 5. **Final Purification**: As the molten zone moves along the rod, the impurities are effectively separated from the pure metal. Eventually, this results in a highly purified metal rod, as the impurities are concentrated in the molten zone and can be removed. 6. **Conclusion**: Thus, the assertion that metals of high purity are obtained by zone refining is correct, and the reasoning that impurities are more soluble in the molten zone than in the pure metal is also correct. The reasoning provides a valid explanation for the assertion.
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Give reasons for the following : (i) Metals can be recovered from their ores by chemical methods. (ii) High purity metals can be obtained by zone refining method. (iii) Why is sodium choride added during electrolysis of fused anhydrous magnesium chloride ? (iv) Why is chalcocite roasted and not calcinated during recovery of copper ?

CENGAGE CHEMISTRY ENGLISH-GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS-Exercise (Assertion-Reasoning)
  1. Assertion: All minerals are ore. Reason: Ores are minerals from whic...

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  2. Argentite ore is concentrated by froth flotation process. Argentite ...

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  3. All metals cannot be obtained by carbon reduction. Carbon is poor re...

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  4. Assertion: Durig calcination the ore is heated well below its melting ...

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  5. A:Oxygen is the most abundant element on the surface of earth. R: Alu...

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  6. A: Highly electropositive metals are extracted by electrolysis of thei...

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  7. Zone refining is used to obtain metals in high degree of purity. Dur...

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  8. Assertion :Ti can be purified by Van Arkel process. Reason: TiI(4) ...

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  9. Assertion: Aluminothermy is used for extraction of chromium form chrom...

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  10. Assertion: Ag and Au are extracted by leaching the ores with a dilute ...

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  11. By froth flotation process, carbonate and hydroxide ores are concentra...

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  12. Standard free energy of formation for Al(2)O(3) and Cr(2)O(3) at 1273 ...

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  13. Metals of high purity are obtained by zone refining. Impurities are ...

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  14. Assertion: Nickel is purified by reaction it with CO. Reason: Impur...

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  15. During reduction of ZnO to Zn, C is more efficient than CO. The stan...

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  16. Graphite is used as anode but diamond is not. There exist free elect...

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  17. Silver may be prepared by using silver coins. In this process, coins a...

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  18. Reduction of Fe(2)O(3) with CO is done below 710^@C. Delta(f) G^(Ө) ...

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