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Assertion: Nickel is purified by reactio...

Assertion: Nickel is purified by reaction it with `CO`.
Reason: Impurities present in nickel form volatile compounds.

A

If both (A) and ( R) are correct and ( R) is the correct explanation of (A).

B

If both (A) and ( R) are correct, but ( R) is not the correct explanation of (A).

C

If (A) is correct, but ( R) is incorrect.

D

If (A) is incorrect, but ( R) is correct.

Text Solution

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The correct Answer is:
**Step-by-Step Text Solution:** 1. **Understanding the Assertion:** The assertion states that nickel is purified by reacting it with carbon monoxide (CO). This is indeed true. Nickel can be purified through a process that involves its reaction with CO. 2. **Understanding the Reason:** The reason given is that the impurities present in nickel form volatile compounds. This is also true. During the purification process, the impurities do not react with carbon monoxide in the same way that nickel does, and as a result, they remain in the solid state while nickel forms a volatile compound. 3. **The Process of Purification:** The purification of nickel is commonly done using the Mond process. In this process, nickel ore is heated in the presence of carbon monoxide. The nickel reacts with CO to form nickel tetracarbonyl (Ni(CO)₄), which is a volatile compound. 4. **Separation of Impurities:** As the nickel forms this volatile compound, the impurities (gangue) present in the ore do not react with CO and remain as solid residues. This allows for the separation of pure nickel from the impurities. 5. **Conclusion:** Therefore, both the assertion and the reason are correct. The assertion is that nickel is purified by reacting with CO, and the reason explains that the impurities form non-volatile residues, which supports the assertion. **Final Answer:** Both the assertion and reason are correct, and the reason is the correct explanation of the assertion. ---

**Step-by-Step Text Solution:** 1. **Understanding the Assertion:** The assertion states that nickel is purified by reacting it with carbon monoxide (CO). This is indeed true. Nickel can be purified through a process that involves its reaction with CO. 2. **Understanding the Reason:** The reason given is that the impurities present in nickel form volatile compounds. This is also true. During the purification process, the impurities do not react with carbon monoxide in the same way that nickel does, and as a result, they remain in the solid state while nickel forms a volatile compound. ...
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CENGAGE CHEMISTRY ENGLISH-GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS-Exercise (Assertion-Reasoning)
  1. Assertion: All minerals are ore. Reason: Ores are minerals from whic...

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  2. Argentite ore is concentrated by froth flotation process. Argentite ...

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  3. All metals cannot be obtained by carbon reduction. Carbon is poor re...

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  4. Assertion: Durig calcination the ore is heated well below its melting ...

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  5. A:Oxygen is the most abundant element on the surface of earth. R: Alu...

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  6. A: Highly electropositive metals are extracted by electrolysis of thei...

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  7. Zone refining is used to obtain metals in high degree of purity. Dur...

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  8. Assertion :Ti can be purified by Van Arkel process. Reason: TiI(4) ...

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  9. Assertion: Aluminothermy is used for extraction of chromium form chrom...

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  10. Assertion: Ag and Au are extracted by leaching the ores with a dilute ...

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  11. By froth flotation process, carbonate and hydroxide ores are concentra...

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  12. Standard free energy of formation for Al(2)O(3) and Cr(2)O(3) at 1273 ...

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  13. Metals of high purity are obtained by zone refining. Impurities are ...

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  14. Assertion: Nickel is purified by reaction it with CO. Reason: Impur...

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  15. During reduction of ZnO to Zn, C is more efficient than CO. The stan...

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  16. Graphite is used as anode but diamond is not. There exist free elect...

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  17. Silver may be prepared by using silver coins. In this process, coins a...

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  18. Reduction of Fe(2)O(3) with CO is done below 710^@C. Delta(f) G^(Ө) ...

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