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Reduction of Fe(2)O(3) with CO is done b...

Reduction of `Fe_(2)O_(3)` with `CO` is done below `710^@C`.
`Delta_(f) G^(Ө)` is negative at this temperature , this process is spontaneous.

A

If both (A) and ( R) are correct and ( R) is the correct explanation of (A).

B

If both (A) and ( R) are correct, but ( R) is not the correct explanation of (A).

C

If (A) is correct, but ( R) is incorrect.

D

If (A) is incorrect, but ( R) is correct.

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AI Generated Solution

The correct Answer is:
To solve the question regarding the reduction of \( \text{Fe}_2\text{O}_3 \) with \( \text{CO} \) below \( 710^\circ C \) and the spontaneity of the process, we can follow these steps: ### Step 1: Understand the Reaction The reaction in question is the reduction of iron(III) oxide (\( \text{Fe}_2\text{O}_3 \)) by carbon monoxide (\( \text{CO} \)). The balanced chemical equation for this reaction is: \[ \text{Fe}_2\text{O}_3 + 3\text{CO} \rightarrow 2\text{Fe} + 3\text{CO}_2 \] ### Step 2: Gibbs Free Energy and Spontaneity For a reaction to be spontaneous, the change in Gibbs free energy (\( \Delta G \)) must be negative: \[ \Delta G < 0 \] This indicates that the reaction can proceed without the input of additional energy. ### Step 3: Temperature Dependence of \( \Delta G \) The problem states that \( \Delta G \) is negative below \( 710^\circ C \). This means that at temperatures lower than \( 710^\circ C \), the reduction of \( \text{Fe}_2\text{O}_3 \) by \( \text{CO} \) is thermodynamically favorable. ### Step 4: Conclusion on Spontaneity Since \( \Delta G \) is negative at temperatures below \( 710^\circ C \), we conclude that the reduction of \( \text{Fe}_2\text{O}_3 \) with \( \text{CO} \) is indeed spontaneous at these temperatures. ### Final Answer Thus, the assertion that the reduction of \( \text{Fe}_2\text{O}_3 \) with \( \text{CO} \) is done below \( 710^\circ C \) because \( \Delta G \) is negative at this temperature is correct. Both the assertion and reason are correct, and the reason correctly explains the assertion.
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CENGAGE CHEMISTRY ENGLISH-GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS-Exercise (Assertion-Reasoning)
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