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Below 1623 K, Al can reduce MgO to Mg, b...

Below `1623 K, Al` can reduce `MgO` to `Mg`, but above `1623 K`, reverse is true.

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To determine whether the statement "Below 1623 K, Al can reduce MgO to Mg, but above 1623 K, the reverse is true" is true or false, we can analyze the thermodynamic principles involved, particularly focusing on Gibbs free energy changes and the Ellingham diagram. ### Step-by-Step Solution: 1. **Understanding the Reduction Reaction**: - The statement suggests that aluminum (Al) can reduce magnesium oxide (MgO) to magnesium (Mg) at temperatures below 1623 K. This means that Al is acting as a reducing agent, while MgO is being reduced. 2. **Oxidation of Aluminum**: - When Al reduces MgO, it itself gets oxidized to aluminum oxide (Al2O3). The balanced chemical reaction for this process can be represented as: \[ 3MgO + 2Al \rightarrow 3Mg + Al_2O_3 \] 3. **Gibbs Free Energy Consideration**: - The feasibility of a reaction can be assessed using Gibbs free energy (ΔG). A reaction is spontaneous if ΔG is negative. - For the reaction to occur, the ΔG for the reduction of MgO must be more negative than the ΔG for the oxidation of Al. 4. **Ellingham Diagram Analysis**: - The Ellingham diagram plots the Gibbs free energy change (ΔG) for the formation of oxides as a function of temperature. - According to experimental data and the Ellingham diagram, the ΔG for the formation of Al2O3 (oxidation of Al) is less negative than that for the formation of MgO (oxidation of Mg) at temperatures below 1623 K. 5. **Conclusion on the Statement**: - Since ΔG for the formation of MgO is more negative than that for Al2O3 at temperatures below 1623 K, aluminum cannot reduce magnesium oxide in this temperature range. - Therefore, the statement that "below 1623 K, Al can reduce MgO to Mg" is **false**. 6. **Reversal Above 1623 K**: - Above 1623 K, the situation reverses. The ΔG for the oxidation of Al becomes more favorable, allowing Al to reduce MgO to Mg. Thus, the reverse statement holds true above this temperature. ### Final Answer: The given statement is **false**.

To determine whether the statement "Below 1623 K, Al can reduce MgO to Mg, but above 1623 K, the reverse is true" is true or false, we can analyze the thermodynamic principles involved, particularly focusing on Gibbs free energy changes and the Ellingham diagram. ### Step-by-Step Solution: 1. **Understanding the Reduction Reaction**: - The statement suggests that aluminum (Al) can reduce magnesium oxide (MgO) to magnesium (Mg) at temperatures below 1623 K. This means that Al is acting as a reducing agent, while MgO is being reduced. 2. **Oxidation of Aluminum**: ...
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CENGAGE CHEMISTRY ENGLISH-GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS-Exercise (True/False)
  1. Levigation is generally employed for concentration of sulphide ores.

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  2. Every mineral is an ore, but every ore is not a mineral.

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  3. Slag is a product formed during smelting by combination of flux and im...

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  4. Alkali metals can be obtained by chemical reduction of their compounds...

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  5. Sylvine is an ore of potassium.

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  6. Oxide ore are purified by levigation process.

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  7. During electrorefining of a metal, impure metal is made anode.

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  8. Highly pure metal can be obtained by zone refining

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  9. Aluminium is the most abundant metal in the earth's crust.

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  10. Reactive metals occur in native state.

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  11. The process of calcination and roasting is carried out in reverberator...

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  12. In calcination, ore is heated strongly in the absence of air

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  13. Copper is found both in free as well as in combined state in nature.

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  14. Below 1623 K, Al can reduce MgO to Mg, but above 1623 K, reverse is tr...

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  15. Mond's process is used for purification of titanium.

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  16. KCN forms soluble complex with silver glance.

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  17. Zinc blende on roasting often gives Zn metal.

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  18. Silver is extracted by hydrometallurgy.

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  19. The lining of blast furnace is made up of fire clay bricks.

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  20. Gypsum is an ore of magnesium.

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