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Assertion (A): ICl on hydrolysis gives H...

Assertion (A): ICl on hydrolysis gives HI and HOCl.
Reason (R ): Water can attack iodine more readily.

A

If both `(A)` and ` (R )` are correct and `(R )` is the correct explanation of `(A ) ` .

B

If both `(A)` and ` (R )` are correct and `(R )` is not the correct explanation of `(A )`

C

If`(A)` is correct, but `( R )` is incorrect .

D

Both `(A)` and `(R ) ` are incorrect .

Text Solution

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The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Assertion The assertion states that "ICl on hydrolysis gives HI and HOCl." We need to evaluate if this statement is true or false. - When ICl (iodine monochloride) undergoes hydrolysis, it reacts with water (H2O). - The expected products of this reaction can be determined by considering the behavior of ICl in the presence of water. ### Step 2: Analyzing the Hydrolysis Reaction The hydrolysis of ICl can be represented as follows: \[ \text{ICl} + \text{H}_2\text{O} \rightarrow \text{HOI} + \text{HCl} \] - In this reaction, iodine (I) is attacked by the hydroxyl ion (OH⁻) from water, while chlorine (Cl) is attacked by the hydrogen ion (H⁺). - The products formed are HOI (hypoiodous acid) and HCl (hydrochloric acid). ### Step 3: Conclusion on the Assertion Since the products of the hydrolysis of ICl are HOI and HCl, and not HI and HOCl as stated in the assertion, we conclude that: - **Assertion (A) is false.** ### Step 4: Understanding the Reason The reason states that "Water can attack iodine more readily." We need to evaluate if this statement is true or false. - Iodine is more electropositive compared to chlorine, which means it has a weaker bond with chlorine in ICl. - This makes iodine more susceptible to attack by nucleophiles, such as the hydroxyl ion from water. ### Step 5: Conclusion on the Reason Given that iodine is indeed more reactive and can be attacked more readily by water, we conclude that: - **Reason (R) is true.** ### Final Conclusion - **Assertion (A) is false.** - **Reason (R) is true.** Thus, the answer to the question is that the assertion is wrong and the reason is correct.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Assertion The assertion states that "ICl on hydrolysis gives HI and HOCl." We need to evaluate if this statement is true or false. - When ICl (iodine monochloride) undergoes hydrolysis, it reacts with water (H2O). - The expected products of this reaction can be determined by considering the behavior of ICl in the presence of water. ...
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