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The set with the correct order of acidit...

The set with the correct order of acidity is

A

`HOCI lt HCIO_(2) lt HCIO_(3)HCIO_(4)`

B

`HCIO_(4) lt HCIO_(3) lt HCIO_(2) lt HOCI`

C

`HOCI lt HCIO_(4) lt HCIO_(3)lt HCIO_(2)`

D

`HCIO_(4) lt HCIO_(2) lt HCIO_(3) lt HOCI`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of acidity for the given acids (HClO, HClO2, HClO3, and HClO4), we need to analyze their conjugate bases and the factors affecting their stability. ### Step-by-Step Solution: 1. **Identify the Acids and Their Conjugate Bases**: - The acids are HClO, HClO2, HClO3, and HClO4. - Their conjugate bases are ClO⁻, ClO2⁻, ClO3⁻, and ClO4⁻ respectively. 2. **Understand the Stability of Conjugate Bases**: - The stability of a conjugate base is crucial in determining the strength of the corresponding acid. A more stable conjugate base indicates a stronger acid. - The stability of these conjugate bases increases with the number of oxygen atoms attached to the chlorine atom. More oxygen atoms can delocalize the negative charge better. 3. **Order of Stability of Conjugate Bases**: - ClO⁻ (from HClO) is the least stable because it has only one oxygen atom. - ClO2⁻ (from HClO2) is more stable than ClO⁻ due to the presence of an additional oxygen atom. - ClO3⁻ (from HClO3) is even more stable than ClO2⁻. - ClO4⁻ (from HClO4) is the most stable conjugate base due to the maximum number of oxygen atoms (four). 4. **Order of Acidity**: - Since the stability of the conjugate base is directly related to the acidity of the acid, we can conclude: - HClO < HClO2 < HClO3 < HClO4 - This means HClO is the weakest acid, while HClO4 is the strongest acid. 5. **Final Conclusion**: - The correct order of acidity is: HClO < HClO2 < HClO3 < HClO4.

To determine the correct order of acidity for the given acids (HClO, HClO2, HClO3, and HClO4), we need to analyze their conjugate bases and the factors affecting their stability. ### Step-by-Step Solution: 1. **Identify the Acids and Their Conjugate Bases**: - The acids are HClO, HClO2, HClO3, and HClO4. - Their conjugate bases are ClO⁻, ClO2⁻, ClO3⁻, and ClO4⁻ respectively. ...
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