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Assertion : XeF(2) is linear Reason :X...

Assertion : `XeF_(2)` is linear
Reason :Xe atom in `XeF_(2)` is sp hybridised

A

If both (A) and (R ) are correct and (R ) is the correct explanation of (A)

B

If both (A) and (R ) are correct,but (R ) is the correct explanation of (A)

C

If (A) is correct but (R ) is incorrect

D

If (A) is incorrect but (R ) is correct

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason about the molecule \( \text{XeF}_2 \), we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states that \( \text{XeF}_2 \) is linear. To determine if this is true, we need to look at the molecular geometry of \( \text{XeF}_2 \). 1. **Determine the Valence Electrons**: - Xenon (Xe) has 8 valence electrons. - Each fluorine (F) contributes 1 valence electron, and there are 2 fluorine atoms, contributing a total of 2 electrons. - Total valence electrons = 8 (from Xe) + 2 (from 2 F) = 10 valence electrons. 2. **Calculate the Steric Number**: - The steric number is calculated as: \[ \text{Steric Number} = \text{Number of Valence Electrons} + \text{Number of Monovalent Species} / 2 \] - Here, the number of monovalent species (F atoms) is 2. - Thus, the steric number = \( 8 + 2 / 2 = 5 \). 3. **Determine the Hybridization**: - A steric number of 5 indicates \( sp^3d \) hybridization. 4. **Molecular Geometry**: - With \( sp^3d \) hybridization and 3 lone pairs and 2 bonding pairs (from the two fluorine atoms), the molecular geometry is based on the arrangement of these pairs. - The two fluorine atoms occupy the axial positions, while the three lone pairs occupy the equatorial positions, leading to a linear shape for the molecule. **Conclusion for Assertion**: The assertion that \( \text{XeF}_2 \) is linear is **correct**. ### Step 2: Analyze the Reason The reason states that the Xe atom in \( \text{XeF}_2 \) is \( sp \) hybridized. 1. **Check the Hybridization**: - As calculated earlier, the steric number of xenon in \( \text{XeF}_2 \) is 5, which corresponds to \( sp^3d \) hybridization, not \( sp \). **Conclusion for Reason**: The reason that the Xe atom in \( \text{XeF}_2 \) is \( sp \) hybridized is **incorrect**. ### Final Conclusion - The assertion is correct: \( \text{XeF}_2 \) is linear. - The reason is incorrect: the Xe atom is \( sp^3d \) hybridized, not \( sp \). ### Summary - **Assertion**: True - **Reason**: False

To solve the question regarding the assertion and reason about the molecule \( \text{XeF}_2 \), we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states that \( \text{XeF}_2 \) is linear. To determine if this is true, we need to look at the molecular geometry of \( \text{XeF}_2 \). 1. **Determine the Valence Electrons**: - Xenon (Xe) has 8 valence electrons. - Each fluorine (F) contributes 1 valence electron, and there are 2 fluorine atoms, contributing a total of 2 electrons. ...
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