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Assertion : XeF(4) is square planar Re...

Assertion : `XeF_(4)` is square planar
Reason :Xe atom in `XeF_(4)` is `dsp^(2)` hybridised

A

If both (A) and (R ) are correct and (R ) is the correct explanation of (A)

B

If both (A) and (R ) are correct,but (R ) is the correct explanation of (A)

C

If (A) is correct but (R ) is incorrect

D

If (A) is incorrect but (R ) is correct

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given assertion and reason question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that `XeF4` is square planar. To verify this, we need to determine the molecular geometry of `XeF4`. 1. **Determine the Valence Electrons**: - Xenon (Xe) has 8 valence electrons. - Each fluorine (F) contributes 1 valence electron, and since there are 4 fluorine atoms, they contribute 4 electrons. - Total valence electrons = 8 (from Xe) + 4 (from 4 F) = 12 valence electrons. 2. **Calculate the Steric Number**: - The steric number is calculated using the formula: \[ \text{Steric Number} = \frac{\text{Number of Valence Electrons} + \text{Number of Monovalent Atoms}}{2} \] - Here, the number of monovalent atoms (F) = 4. - Therefore, the steric number = \(\frac{12}{2} = 6\). 3. **Determine the Hybridization**: - A steric number of 6 corresponds to `sp^3d^2` hybridization (not `dsp^2`). 4. **Molecular Geometry**: - With `sp^3d^2` hybridization and 4 bonded pairs (from 4 F atoms) and 2 lone pairs on the Xe atom, the molecular geometry is square planar. ### Conclusion for Assertion: - The assertion that `XeF4` is square planar is **correct**. ### Step 2: Analyze the Reason The reason states that the Xe atom in `XeF4` is `dsp^2` hybridized. 1. **Check the Hybridization**: - As calculated earlier, the hybridization for `XeF4` is `sp^3d^2`, not `dsp^2`. - `dsp^2` hybridization corresponds to a steric number of 4, which does not apply here. ### Conclusion for Reason: - The reason that the Xe atom in `XeF4` is `dsp^2` hybridized is **incorrect**. ### Final Conclusion: - The assertion is correct, but the reason is incorrect. ### Summary: - **Assertion**: `XeF4` is square planar - **Correct** - **Reason**: Xe atom in `XeF4` is `dsp^2` hybridized - **Incorrect**

To solve the given assertion and reason question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that `XeF4` is square planar. To verify this, we need to determine the molecular geometry of `XeF4`. 1. **Determine the Valence Electrons**: - Xenon (Xe) has 8 valence electrons. - Each fluorine (F) contributes 1 valence electron, and since there are 4 fluorine atoms, they contribute 4 electrons. ...
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