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Which of the possible following florides...

Which of the possible following florides of xenon is impossible ?

A

`XeF_(2)`

B

`XeF_(4)`

C

`XeF_(6)`

D

`XeF_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the fluorides of xenon is impossible, we need to analyze the steric numbers and hybridization of each compound. Let's go through the options step by step. ### Step 1: Analyze XeF2 - **Valence Electrons**: Xenon has 8 valence electrons. - **Fluorine Atoms**: There are 2 fluorine atoms, each contributing 1 electron. - **Steric Number Calculation**: \[ \text{Steric Number} = \frac{\text{Valence Electrons} + \text{Number of Monovalent Atoms}}{2} = \frac{8 + 2}{2} = 5 \] - **Hybridization**: The hybridization corresponding to a steric number of 5 is sp³d. - **Conclusion**: XeF2 is possible. ### Step 2: Analyze XeF4 - **Valence Electrons**: Xenon has 8 valence electrons. - **Fluorine Atoms**: There are 4 fluorine atoms. - **Steric Number Calculation**: \[ \text{Steric Number} = \frac{8 + 4}{2} = 6 \] - **Hybridization**: The hybridization for a steric number of 6 is sp³d². - **Conclusion**: XeF4 is possible. ### Step 3: Analyze XeF6 - **Valence Electrons**: Xenon has 8 valence electrons. - **Fluorine Atoms**: There are 6 fluorine atoms. - **Steric Number Calculation**: \[ \text{Steric Number} = \frac{8 + 6}{2} = 7 \] - **Hybridization**: The hybridization for a steric number of 7 is sp³d³. - **Conclusion**: XeF6 is possible. ### Step 4: Analyze XeF3 - **Valence Electrons**: Xenon has 8 valence electrons. - **Fluorine Atoms**: There are 3 fluorine atoms. - **Steric Number Calculation**: \[ \text{Steric Number} = \frac{8 + 3}{2} = \frac{11}{2} = 5.5 \] - **Conclusion**: A fractional steric number (5.5) is not possible, indicating that XeF3 cannot be formed. ### Final Answer The impossible fluoride of xenon is **XeF3**. ---

To determine which of the fluorides of xenon is impossible, we need to analyze the steric numbers and hybridization of each compound. Let's go through the options step by step. ### Step 1: Analyze XeF2 - **Valence Electrons**: Xenon has 8 valence electrons. - **Fluorine Atoms**: There are 2 fluorine atoms, each contributing 1 electron. - **Steric Number Calculation**: \[ \text{Steric Number} = \frac{\text{Valence Electrons} + \text{Number of Monovalent Atoms}}{2} = \frac{8 + 2}{2} = 5 ...
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