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Identify A to C. (a). An aqueous solut...

Identify A to C.
(a). An aqueous solution of a compoud (A) is acidic towards litmus and (A) is sublimed at about `300^@C`.
(b). (A) on treatment with an excess of `NH_4CNC` gives a red coloured compound (B) and on treatment with a solution of `K_4Fe(CN)_6` gives a blue coloured compound (C).

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To solve the given problem, we need to identify the compounds A, B, and C based on the information provided. Let's break down the steps: ### Step 1: Identify Compound A - The question states that an aqueous solution of compound A is acidic towards litmus and that A sublimes at about 300°C. - A common compound that fits this description is **Iron(III) chloride (FeCl₃)**. - When dissolved in water, FeCl₃ dissociates to release HCl, making the solution acidic. **Hint:** Look for a compound that is both acidic in solution and has a sublimation point around 300°C. ...
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(i) An aqueous solution of a compound (A) is acidic towards litmus and (A) sublimes at about 300^(@)C . (ii) (A) on treatment with an excess of NH_(4)SCN gives a red coloured compound (B) and on treatment with a solution of K_(4)[Fe(CN)_(6)] gives a blue coloured compound (C). (iii) (A) on heating with excess of K_(2)Cr_(2)O_(7) in the presence of concentrated H_(2)SO_(4) evolves deep red vapours of (D). (iv) On passing the vapour of (D) into a solution of NaOH and then adding the solution of acetic acid and lead acetate, a yellow precipitate of compound (E) is obtained. Identify (A) to (E) and give chemical equations for the reactions.

(i) An aqueous solution of a compound (A) is acidic towards litmus and (A) sublimes at about 300^(@)C . (ii) (A) on treatment with an excess of NH_(4)SCN gives a red coloured compound (B) and on treatment with a solution of K_(4)[Fe(CN)_(6)] gives a blue coloured compound (C). (iii) (A) on heating with excess of K_(2)Cr_(2)O_(7) in the presence of concentrated H_(2)SO_(4) evolves deep red vapours of (D). (iv) On passing the vapour of (D) into a solution of NaOH and then adding the solution of acetic acid and lead acetate, a yellow precipitate of compound (E) is obtained. Identify (A) to (E) and give chemical equations for the reactions.

(i) An aqueous solution of a compound A is acidic towards litmus and A sublimes at about 300^(@)C (ii) A solution of A, on treatment with an excess of NH_(4)SCN , gives a red compound, and on treatment with a solution of K_(4)[Fe(CN)_(6)] , gives a blue compound. (iii) The solid A, on being heated with an excess of K_(2)Cr_(2)O_(7) in the presence of concentrated H_(2)SO_(4) , evolves deep red vapours of D. (iv) On passing the vapours of D into a solution of NaOH and then adding the solution of acetic acid and lead acetate, a yellow precipitate of a compound E is obtained. Q. Can compound A be prepared in the anhydrous form by strongly heating its hydrated crystals?

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