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How the following conversions are made? ...

How the following conversions are made?
(a). Copper chloride from copper nitrate.
(b). Cuprous oxide from copper sulphate.
(c). Cuprous oxide from copper.

Text Solution

Verified by Experts

`Cu(NO_3)_2+2NaOHtounderset(ppt.)(Cu(OH)_2)+2NaNO_3`
`Cu(OH)_2+2HCitoCuCl_2+2H_2O`
(b). `CuSO_4+2NaOHtounderset(ppt.)(Cu(OH)_2)+Na_2SO_4`
`Cu(OH)_2underset(heated)overset(strongly)toCuO+H_2O`
`CuO+Cuoverset(heat)toCu_2O`
or `CuSO_4to` Fehling['s solution
`C_6H_(12)O+6+` fehling's soln. `Cu_2O+C_6H_(12)O_7`
(c) `Cu+4HNO_3(conc.)toCu(NO_3)_2+2NO_2+2H_2O`
`2Cu(NO_3)_2overset(heat)to2CuO+2CuO+4NO_2+O_2`
`CuO+Cuoverset(heat)toCu_2O`
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