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Among the following series of transition...

Among the following series of transition metal ions the one where all meal ions have `3d^2` electronic configuration is

A

`Ti^(3+),V^(2+),Cr^(3+),Mn^(4+)`

B

`Ti^(o+),V^(4+),Cr^(6+),Mn^(7+)`

C

`Ti^(4+),V^(3+),Cr^(2+),Mn^(3+)`

D

`Ti^(2+),V^(3+),Cr^(4+),Mn^(5+)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of which transition metal ion has a `3d^2` electronic configuration, we will analyze the electronic configurations of the given transition metals and their oxidation states. ### Step-by-Step Solution: 1. **Identify the Atomic Numbers and Electronic Configurations:** - Titanium (Ti): Atomic number 22, electronic configuration: `1s² 2s² 2p⁶ 3s² 3p⁶ 3d² 4s²` - Vanadium (V): Atomic number 23, electronic configuration: `1s² 2s² 2p⁶ 3s² 3p⁶ 3d³ 4s²` - Chromium (Cr): Atomic number 24, electronic configuration: `1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁵ 4s¹` (note the exceptional configuration) - Manganese (Mn): Atomic number 25, electronic configuration: `1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁵ 4s²` 2. **Determine the Oxidation States:** - For each metal, we will find the oxidation states where the remaining electrons correspond to a `3d²` configuration. 3. **Titanium (Ti):** - In the +2 oxidation state: - Remove 2 electrons from `4s²`: `3d² 4s⁰` → Configuration: `3d²` - Thus, Ti²⁺ has a `3d²` configuration. 4. **Vanadium (V):** - In the +3 oxidation state: - Remove 3 electrons (2 from `4s²` and 1 from `3d³`): `3d² 4s⁰` → Configuration: `3d²` - Thus, V³⁺ has a `3d²` configuration. 5. **Chromium (Cr):** - In the +6 oxidation state: - Remove 6 electrons (1 from `4s¹` and 5 from `3d⁵`): `3d⁰ 4s⁰` → Configuration: `3d²` - Thus, Cr⁶⁺ does not have `3d²` configuration. - In the +4 oxidation state: - Remove 4 electrons (1 from `4s¹` and 3 from `3d⁵`): `3d² 4s⁰` → Configuration: `3d²` - Thus, Cr⁴⁺ has a `3d²` configuration. 6. **Manganese (Mn):** - In the +5 oxidation state: - Remove 5 electrons (2 from `4s²` and 3 from `3d⁵`): `3d² 4s⁰` → Configuration: `3d²` - Thus, Mn⁵⁺ has a `3d²` configuration. 7. **Conclusion:** - The transition metal ions that have `3d²` electronic configuration in their respective oxidation states are: - Titanium (Ti²⁺) - Vanadium (V³⁺) - Chromium (Cr⁴⁺) - Manganese (Mn⁵⁺) ### Final Answer: The correct answer is **Titanium (Ti²⁺), Vanadium (V³⁺), Chromium (Cr⁴⁺), and Manganese (Mn⁵⁺)**, where all metal ions have `3d²` electronic configuration.

To solve the question of which transition metal ion has a `3d^2` electronic configuration, we will analyze the electronic configurations of the given transition metals and their oxidation states. ### Step-by-Step Solution: 1. **Identify the Atomic Numbers and Electronic Configurations:** - Titanium (Ti): Atomic number 22, electronic configuration: `1s² 2s² 2p⁶ 3s² 3p⁶ 3d² 4s²` - Vanadium (V): Atomic number 23, electronic configuration: `1s² 2s² 2p⁶ 3s² 3p⁶ 3d³ 4s²` - Chromium (Cr): Atomic number 24, electronic configuration: `1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁵ 4s¹` (note the exceptional configuration) ...
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