Home
Class 12
CHEMISTRY
Assertion: Equivalent mass of KMnO4 is s...

Assertion: Equivalent mass of `KMnO_4` is same in the neutral as well as alkaline medium.
Reason: The product formed in both cases in `MnO_2`

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect.

D

If (A) is incorrect but (R) is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion and reasoning question regarding the equivalent mass of KMnO4 in neutral and alkaline mediums, we will analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the equivalent mass of KMnO4 is the same in both neutral and alkaline mediums. - To evaluate this, we need to look at the half-reactions that occur in both mediums and determine the number of electrons transferred. 2. **Half-Reaction in Alkaline Medium**: - In alkaline medium, the half-reaction for the reduction of permanganate ion (MnO4^-) can be written as: \[ \text{MnO}_4^- + 2 \text{H}_2\text{O} + 3 \text{e}^- \rightarrow \text{MnO}_2 + 4 \text{OH}^- \] - Here, 3 electrons are transferred. 3. **Calculating Equivalent Mass in Alkaline Medium**: - The equivalent mass (E) can be calculated using the formula: \[ E = \frac{\text{Molar mass}}{\text{Number of electrons transferred}} \] - The molar mass of KMnO4 is 158 g/mol. Therefore, in alkaline medium: \[ E = \frac{158}{3} \approx 52.7 \text{ g/equiv} \] 4. **Half-Reaction in Neutral Medium**: - In neutral medium, the half-reaction is: \[ \text{MnO}_4^- + 4 \text{H}^+ + 3 \text{e}^- \rightarrow \text{MnO}_2 + 2 \text{H}_2\text{O} \] - Again, 3 electrons are transferred. 5. **Calculating Equivalent Mass in Neutral Medium**: - Using the same formula for equivalent mass: \[ E = \frac{158}{3} \approx 52.7 \text{ g/equiv} \] 6. **Conclusion on Assertion**: - Since the equivalent mass of KMnO4 is the same in both neutral and alkaline mediums (52.7 g/equiv), the assertion is **true**. 7. **Understanding the Reason**: - The reason states that the product formed in both cases is MnO2. - While this statement is also true, it does not explain why the equivalent mass is the same. The equivalent mass depends on the number of electrons transferred, not solely on the product formed. 8. **Conclusion on Reason**: - The reason is **true**, but it does not correctly explain the assertion. ### Final Answer: - The assertion is true, and the reason is true but does not provide the correct explanation for the assertion.
Promotional Banner

Topper's Solved these Questions

  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer|10 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Fill In The Blanks|9 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct Compounds Of Transition Elements (Miscellaneous Compounds)|21 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|18 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archieves Subjective|35 Videos

Similar Questions

Explore conceptually related problems

The equivalent mass of KMnO_4 in alkaline and neutral mediums is ul"one-fifth" of its molecular mass.

Assertion: KMnO_(4) has different equivalent wieghts in acid, neutral or alkaline medium. Reason: In different, change in oxidation number shown by maganese is altogether different.

2 moles of KMnO_(4) can oxidise x moles of hydrogen peroxide in weakly alkaline medium. Find x

Equivalent mass of Ba(MnO_(4))_(2) in acidic medium is :(where M stands for molar mass)

When KMnO_4 reacts with I^- in a slightly alkaline and acidic medium, the respective products obtained are

Assertion :- Equivalent weight of KMnO_(4) in acidic medium is M//5 (M=molecular weight) while in basic medium, it is equal of M/3. Reason :- In acidic medium, 1 mol of MnO_(4)^(-) gains 5 mole electrons while in basic medium it gains 3 mole electrons.

(a). IF both (A) and (R) are correct and (R) is the correct explanation of (A). (b). If both (A) and (R) are correct but (R) is not the correct explanation of (A). (c). If (A) is correct, but (R) is incorrect. (d). If (A) is incorrect, but (R) is correct. ltbr. (e) if both (A) and (R) are incorrect. Q. Assertion (A): Equivalent mass of KMnO_(4) is equal to one-fifth of its molecular mass when it acts as oxidising agent in mild basic medium. Reason (R): Oxidation number of Mn in KMnO_(4) is +7 .

MnO_(4)^(2-) ( 1 mole) in neutral aqueous medium is disproportionate to

Assertion: KMnO_(4) is purple in colour due to charge transfer . Reason :There is no electron present in d-orbitals of maganese in MnO_(4)^(-))

Assertion: KMnO_(4) is purple in colour due to charge transfer . Reason :There is no electron present in d-orbitals of maganese in MnO_(4)^(-))

CENGAGE CHEMISTRY ENGLISH-D AND F BLOCK ELEMENTS-Exercises Assertion Reasoning
  1. Assertion: The second ionisation energies of V, Cr and Mn are in the o...

    Text Solution

    |

  2. Metal-metal bonding is more frequent in 4d or 5d series than in 3d ser...

    Text Solution

    |

  3. Assertion: Mercuryis not considered as a transition element. Reason:...

    Text Solution

    |

  4. Assertion: Ti^(3+) salts are coloured whereas Ti^(4+) salts are white....

    Text Solution

    |

  5. Assertion: Cu, Ag and Au lie in Group 11 of the periodic table. Hence ...

    Text Solution

    |

  6. Assertion : K(2)Cr(2)O(7) is used as primary standard in volumetric an...

    Text Solution

    |

  7. Statement-1: Tungsten has very high melting point Statament-2: Tungs...

    Text Solution

    |

  8. Assertion: Manganese shows a number of oxidation states. Reason: The...

    Text Solution

    |

  9. Assertion: Equivalent mass of KMnO4 is same in the neutral as well as ...

    Text Solution

    |

  10. Assertion: In Cr2O7^(2-) ion, all the Cr-O bond lengths are equal. R...

    Text Solution

    |

  11. Assertion: In any transition series the magnetic moment of M^(2+) io...

    Text Solution

    |

  12. Assertion: MnO is basic whereas Mn2O7 is acidic. Reason: Higher the ...

    Text Solution

    |

  13. Assertion : Ce^(4+) is used as an oxidising agent in volumetric analys...

    Text Solution

    |

  14. Statament-1: Mn atom loses ns electrons first during ionisation as co...

    Text Solution

    |

  15. Assertion: Actinoids show greater number of oxidation states than lant...

    Text Solution

    |

  16. Assertion : E^(@)" for"Mn^(3+)//Mn^(2+) is more positve than Cr^(3+)//...

    Text Solution

    |

  17. Assertion: The spin only magnetic moment of Sc^(3+) is 1.73 BM. Reas...

    Text Solution

    |

  18. Assertion: An aqueous solution of FeCl3 is acidic. Reason: It is due...

    Text Solution

    |

  19. Assertion: La should be the f-block element according to Aufbau princi...

    Text Solution

    |

  20. Assertion: Mercurous compounds are diamagnetic. Reason: Two Hg^(o+) ...

    Text Solution

    |