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Assertion: In Cr2O7^(2-) ion, all the Cr...

Assertion: In `Cr_2O_7^(2-)` ion, all the `Cr-O` bond lengths are equal.
Reason: In `Cr_2O_7^(2-)` ion all the `O-Cr-O` bond angles are equal.

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect.

D

If (A) is incorrect but (R) is incorrect.

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The correct Answer is:
To solve the question regarding the assertion and reason about the `Cr_2O_7^(2-)` ion, let's break it down step by step. ### Step 1: Analyze the Assertion The assertion states that in the `Cr_2O_7^(2-)` ion, all the `Cr-O` bond lengths are equal. To evaluate this, we need to consider the structure of the dichromate ion. - The `Cr_2O_7^(2-)` ion has a specific structure where two chromium atoms are bonded to seven oxygen atoms. - In this structure, there are both single and double bonds between chromium and oxygen. Specifically, there are two `Cr=O` double bonds and five `Cr-O` single bonds. **Conclusion for Step 1:** Since there are different types of bonds (single and double), the bond lengths cannot be equal. Therefore, the assertion is **incorrect**. ### Step 2: Analyze the Reason The reason states that in the `Cr_2O_7^(2-)` ion, all the `O-Cr-O` bond angles are equal. - The `Cr_2O_7^(2-)` ion has a symmetrical structure. The bond angles around each chromium atom are influenced by the arrangement of the surrounding oxygen atoms. - In the case of the `Cr_2O_7^(2-)` ion, the geometry is such that the `O-Cr-O` bond angles are indeed equal due to the symmetrical arrangement of the oxygen atoms around the chromium atoms. **Conclusion for Step 2:** The reason is **correct**. ### Final Conclusion - The assertion is **incorrect**. - The reason is **correct**. Thus, the correct answer to the question is that the assertion is false while the reason is true.

To solve the question regarding the assertion and reason about the `Cr_2O_7^(2-)` ion, let's break it down step by step. ### Step 1: Analyze the Assertion The assertion states that in the `Cr_2O_7^(2-)` ion, all the `Cr-O` bond lengths are equal. To evaluate this, we need to consider the structure of the dichromate ion. - The `Cr_2O_7^(2-)` ion has a specific structure where two chromium atoms are bonded to seven oxygen atoms. - In this structure, there are both single and double bonds between chromium and oxygen. Specifically, there are two `Cr=O` double bonds and five `Cr-O` single bonds. ...
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