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Assertion: The spin only magnetic moment...

Assertion: The spin only magnetic moment of `Sc^(3+)` is 1.73 BM.
Reason: The spin only magnetic momentum in (BM) is equal to `sqrt(n(n+2))`.

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect.

D

If (A) is incorrect but (R) is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that the spin-only magnetic moment of Sc^(3+) is 1.73 BM (Bohr Magnetons). **Hint:** Recall that the magnetic moment is related to the number of unpaired electrons in an atom or ion. ### Step 2: Determine the Electronic Configuration of Scandium Scandium (Sc) has the atomic number 21. Its electronic configuration is: \[ \text{Sc: } [\text{Ar}] 4s^2 3d^1 \] **Hint:** Remember that the electronic configuration helps us determine how many electrons are present in each subshell. ### Step 3: Determine the Configuration of Sc^(3+) When Sc loses three electrons to form Sc^(3+), it loses the two 4s electrons and the one 3d electron. Thus, the electronic configuration of Sc^(3+) becomes: \[ \text{Sc}^{3+}: [\text{Ar}] \] **Hint:** Identify which electrons are lost when forming cations. ### Step 4: Identify Unpaired Electrons in Sc^(3+) Since Sc^(3+) has the electronic configuration of argon, it has no unpaired electrons. **Hint:** Unpaired electrons are crucial for determining magnetic properties. ### Step 5: Calculate the Spin-Only Magnetic Moment The formula for the spin-only magnetic moment is: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. Since \( n = 0 \) for Sc^(3+): \[ \mu = \sqrt{0(0 + 2)} = \sqrt{0} = 0 \, \text{BM} \] **Hint:** Substitute the value of \( n \) into the formula to find the magnetic moment. ### Step 6: Conclusion on the Assertion Since the calculated spin-only magnetic moment is 0 BM and not 1.73 BM as stated in the assertion, the assertion is false. ### Step 7: Analyze the Reason The reason states that the spin-only magnetic moment in BM is equal to \( \sqrt{n(n + 2)} \). This statement is correct. **Hint:** Verify if the formula for calculating magnetic moment is accurate. ### Final Conclusion - **Assertion:** False (the spin-only magnetic moment of Sc^(3+) is 0 BM, not 1.73 BM) - **Reason:** True (the formula for calculating the magnetic moment is correct) Thus, the correct answer is that the assertion is wrong and the reason is correct. ### Summary of Steps: 1. Analyze the assertion about Sc^(3+). 2. Determine the electronic configuration of Sc. 3. Find the configuration of Sc^(3+). 4. Identify the number of unpaired electrons. 5. Calculate the spin-only magnetic moment. 6. Conclude the truth of the assertion. 7. Verify the reason.
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