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Which of the following represent the cor...

Which of the following represent the correct sequence of indicated property ? .

A

`a.Mn^(2+)ltNi^(2+)ltCo^(2+)ltFe^(2+)`: magnetic moment

B

`b.FeOgtCoOgtNiO`:basic character

C

`c.ScltTiltCrltMn`: number of oxidation states

D

`d.1.73mu:` one unpaired electrons

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the correct sequence of indicated properties among the given options, we will analyze each property step by step. ### Step-by-Step Solution: 1. **Magnetic Moment Calculation**: - The magnetic moment is calculated using the formula: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. - For the given transition metals: - **Mn²⁺**: Configuration is \( 3d^5 \) → 5 unpaired electrons. - **Fe²⁺**: Configuration is \( 3d^6 \) → 4 unpaired electrons. - **Co²⁺**: Configuration is \( 3d^7 \) → 3 unpaired electrons. - **Ni²⁺**: Configuration is \( 3d^8 \) → 2 unpaired electrons. - Thus, the order of magnetic moments based on unpaired electrons is: \[ \text{Mn²⁺} > \text{Fe²⁺} > \text{Co²⁺} > \text{Ni²⁺} \] 2. **Basic Character of Oxides**: - The basic character of oxides decreases from left to right across the periodic table due to decreasing electropositivity. - The order of basic character for the oxides is: \[ \text{FeO} > \text{CoO} > \text{NiO} \] 3. **Oxidation States**: - The oxidation states of the 3d series elements increase up to manganese and then start to decrease. - The order of maximum oxidation states is: \[ \text{Mn} > \text{Cr} > \text{Ti} > \text{Sc} \] - This means manganese has the highest oxidation state, followed by chromium, titanium, and scandium. 4. **Magnetic Moment for 1 Unpaired Electron**: - If there is 1 unpaired electron, the magnetic moment can be calculated as: \[ \mu = \sqrt{1(1 + 2)} = \sqrt{3} \approx 1.732 \] ### Conclusion: Based on the analysis: - The order for magnetic moments is Mn²⁺ > Fe²⁺ > Co²⁺ > Ni²⁺. - The order for basic character of oxides is FeO > CoO > NiO. - The order for oxidation states is Mn > Cr > Ti > Sc. - The magnetic moment for 1 unpaired electron is approximately 1.732. Thus, the correct sequence of the indicated properties is: 1. Magnetic Moment: Mn²⁺ > Fe²⁺ > Co²⁺ > Ni²⁺ 2. Basic Character: FeO > CoO > NiO 3. Oxidation States: Mn > Cr > Ti > Sc 4. Magnetic Moment for 1 unpaired electron: 1.732

To solve the question regarding the correct sequence of indicated properties among the given options, we will analyze each property step by step. ### Step-by-Step Solution: 1. **Magnetic Moment Calculation**: - The magnetic moment is calculated using the formula: \[ \mu = \sqrt{n(n + 2)} ...
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