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Select the correct IUPAC name for [Ti...

Select the correct `IUPAC` name for
`[Ti (pi - C_(5)H_(5))_(2)(O -C_(5)H_(5))_(2)]` .

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The correct Answer is:
To determine the correct IUPAC name for the complex \([Ti (π - C_{5}H_{5})_{2}(O - C_{5}H_{5})_{2}]\), we can follow these steps: ### Step 1: Identify the ligands The complex contains: - Two cyclopentadienyl (C5H5) ligands that are bonded via π (pi) bonds. - Two alkoxide (O-C5H5) ligands that are bonded via sigma (σ) bonds. ### Step 2: Determine the hapticity of the ligands The cyclopentadienyl ligands are bonded in an η^5 (eta 5) manner, which means they are acting as pentadentate ligands. This is indicated by the notation "η^5" in the name. ### Step 3: Count the number of each type of ligand - There are two cyclopentadienyl ligands, so we will use "bis" to indicate two of them. - There are also two alkoxide ligands. ### Step 4: Construct the name The IUPAC name is constructed by listing the ligands in alphabetical order, followed by the metal and its oxidation state. 1. The cyclopentadienyl ligands will be named as "bis(η^5-cyclopentadienyl)". 2. The alkoxide ligands will be named as "bis(alkoxide)" or "bis(cyclopentyl oxide)". 3. The metal is titanium (Ti). ### Step 5: Determine the oxidation state of titanium In this complex, titanium is in its +4 oxidation state. ### Final IUPAC Name Putting it all together, the correct IUPAC name for the complex is: **bis(η^5-cyclopentadienyl)bis(cyclopentyl oxide)titanium(IV)**
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CENGAGE CHEMISTRY ENGLISH-COORDINATION COMPOUNDS-Exercises Single Correct (Naming And Terminology)
  1. Select the correct IUPAC name for [Ti (pi - C(5)H(5))(2)(O -C(5)H(5...

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  2. Select the correct IUPA name of [Mo(sigma -C(3)H(5))(pi - C(5)H(5))(...

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  3. IUPAC name for [Fe(CO)(2)(sigma-C(5)H(5))(pi -C(5)H(5))] complex :

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  4. Select the correct IUPA name for [Cr(C(6)H(6))(CO)(3)] .

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  5. IUPAC name for complex [Mn(pi-C(6)H(5))(CO)(3)]:

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  6. Ligand with two or more points of attachment to single metal atoms are...

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  7. The number of ions produced by the complex [Cr(NH(3))(4)CI(2)]CIO(3) i...

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  8. Which of the following is a tridentate ligand?

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  9. Coordination number of calcium is six in .

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  10. Coordination number of Cu^(2+) in CuSO(4).5H(2)O is .

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  11. The colsed ring compounds formed by bidentate ligands on binding to a ...

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  12. Which is the pair of ambidentate ligand?

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  13. Number of water molecules acting as ligands in CuSO(4).5H(2)O,ZnSO(4...

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  14. Select the correct IUPA name for [Pt(C(5)H(5)N)(4)[[PtCI(4)] complex

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  15. Select the correct IUPAC name of [C(4)H(4)Fe(CO)(3)] complex .

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  16. Oxidation state of "V" in Rb(4)K[HV(10)O(28)] is .

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  17. Coordination number of Cr is six A complex with C(2)O(4)^(2-) en and s...

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  18. The compound [CoCI(3)I(C(5)H(5)N)(2)] Br will show the chemical test f...

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  19. The correct IUPAC name of [Mn(3)(CO)(12)] is .

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  20. The correct name of .

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