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Select the correct IUPA name for [Pt(C...

Select the correct `IUPA` name for
`[Pt(C_(5)H_(5)N)_(4)[[PtCI_(4)]` complex

A

Tetrapyridineplatinate(II)tetrachloridoplatinate(II)

B

Tetrapyridineplatinate(II)tetrachloridoplatinate(II)

C

Tetrapyridineplatinate(II)tetrachloridoplatinate(II)

D

Tetrapyridineplatinum(II)tetrachloridoplatinate(II)

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct IUPAC name for the coordination compound \([Pt(C_5H_5N)_4][PtCl_4]\), we will follow a systematic approach to naming coordination complexes. ### Step-by-Step Solution: 1. **Identify the Components**: - The complex consists of a cationic part \([Pt(C_5H_5N)_4]^2+\) and an anionic part \([PtCl_4]^{2-}\). - The ligand \(C_5H_5N\) is pyridine, and the ligand \(Cl\) is chlorido. 2. **Count the Ligands**: - There are four pyridine ligands in the cationic part. The prefix for four is "tetra". - There are four chlorido ligands in the anionic part. The prefix for four is also "tetra". 3. **Name the Ligands**: - The ligand pyridine is named as "pyridine". - The ligand chlorido is named as "chlorido". 4. **Name the Cationic Part**: - The central metal in the cationic part is platinum (Pt). - Since the oxidation state of platinum in the cationic part is +2, we simply name it "platinum". 5. **Name the Anionic Part**: - The central metal in the anionic part is also platinum (Pt), but since it is part of an anionic complex, we use the suffix "platinate". - The oxidation state of platinum in the anionic part is +2, which we denote as "platinate(II)". 6. **Combine the Names**: - The full name of the cationic part is "tetrapyridine platinum(II)". - The full name of the anionic part is "tetrachlorido platinate(II)". - When combining these, we write the cationic part first followed by the anionic part. 7. **Final IUPAC Name**: - The complete IUPAC name for the coordination compound is: \[ \text{tetrapyridine platinum(II) tetrachlorido platinate(II)} \]
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CENGAGE CHEMISTRY ENGLISH-COORDINATION COMPOUNDS-Exercises Single Correct (Naming And Terminology)
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