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Select the correct IUPAC name of [C(4)H(...

Select the correct `IUPAC` name of `[C_(4)H_(4)Fe(CO)_(3)]` complex .

A

`eta^(4)`-cyclebutadiene tricarbonyliron(0)

B

Tricarbonyl `(eta^(4)`-cyclobutadienyl)iron(0)

C

Tricarbonyl `(eta^(4)`-cyclobutadienyl)iron(1)

D

Tricarbonyl `(eta^(4)`-cyclobutadienyl)iron(0)

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct IUPAC name of the complex \([C_{4}H_{4}Fe(CO)_{3}]\), we will follow these steps: ### Step 1: Identify the Ligands The complex contains two types of ligands: 1. Carbon monoxide (CO) - a neutral ligand. 2. Cyclobutadiene (\(C_4H_4\)) - a neutral ligand that acts as a \(\eta^4\) (pi-acceptor) ligand. ### Step 2: Determine the Oxidation State of the Metal Since both ligands (CO and cyclobutadiene) are neutral, the oxidation state of iron (Fe) in this complex is 0. ### Step 3: Naming the Ligands According to IUPAC naming conventions: - For the three CO ligands, we use the prefix "tri" to indicate there are three of them. Thus, we name it "tricarbonyl". - For the cyclobutadiene ligand, since it is a \(\eta^4\) ligand, we denote it as "eta to the power 4 cyclobutadiene". ### Step 4: Combine the Names Now we combine the names of the ligands with the name of the metal and its oxidation state: - The name of the metal (iron) is followed by its oxidation state in Roman numerals (0). - Therefore, the complete name becomes "tricarbonyl eta to the power 4 cyclobutadiene iron(0)". ### Final Answer The correct IUPAC name of the complex \([C_{4}H_{4}Fe(CO)_{3}]\) is: **tricarbonyl eta to the power 4 cyclobutadiene iron(0)**. ---
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CENGAGE CHEMISTRY ENGLISH-COORDINATION COMPOUNDS-Exercises Single Correct (Naming And Terminology)
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