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Ag^(o+) forms complexes some of these ar...

`Ag^(o+)` forms complexes some of these are
`[Ag(NH_(3))_(2)]^(o+),2[Ag(CN)_(2)]^(Θ),[Ag(S_(2)O_(3))_(2)]^(3-)`
Which of the following statements is true? .

A

In these complexes, `Ag^(o+)` is a Lewis bese .

B

The hybrisation `Ag^(o+)` is `sp^(2)` .

C

The `Ag^(o+)` complexes are good reducing agents.

D

These complexes are all linear .

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The correct Answer is:
To solve the question regarding the complexes formed by Ag^+ and determine which statement is true, we can follow these steps: ### Step 1: Identify the nature of Ag^+ Ag^+ is a transition metal cation that can act as a Lewis acid. This means it can accept electron pairs from ligands. **Hint:** Remember that Lewis acids accept electrons, while Lewis bases donate electrons. ### Step 2: Analyze the coordination number In the given complexes, we see that Ag^+ forms complexes with different ligands. The coordination number for Ag^+ in these complexes is typically 2, as it can form two bonds with ligands. **Hint:** Coordination number is determined by the number of ligand atoms that are directly bonded to the central metal atom. ### Step 3: Determine the hybridization Since Ag^+ has a coordination number of 2, the hybridization is sp. This results in a linear geometry for the complexes. **Hint:** The hybridization can be determined from the coordination number: 2 corresponds to sp hybridization. ### Step 4: Evaluate the stability of the complexes The complexes formed by Ag^+ are stable due to its electronic configuration. As a d10 metal, it is stable and does not easily undergo oxidation. **Hint:** Stability of complexes can often be related to the electron configuration of the metal ion. ### Step 5: Analyze the options Now, we can evaluate the statements provided in the question: 1. Ag^+ is a Lewis base - **False** (Ag^+ is a Lewis acid) 2. The hybridization of Ag^+ is sp2 - **False** (It is sp) 3. The Ag^+ complexes are good reducing agents - **False** (They are stable and not good reducing agents) 4. All complexes are linear due to sp hybridization - **True** (This is correct) ### Conclusion The correct statement is that all complexes formed by Ag^+ are linear due to its sp hybridization. **Final Answer:** The correct statement is: "All complexes are linear due to sp hybridization." ---
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