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Assertion Metal carbonyls can be called ...

Assertion Metal carbonyls can be called organometallics
Reason Metal carbonyls do contain metal carbon bond .

A

If both `(A)` and ` (R )` are correct and `(R )` is the correct explanation of `(A ) ` .

B

If both `(A)` and ` (R )` are correct and `(R )` is the correct explanation of `(A ) ` .

C

If`(A)` is correct, but `( R )` is incorrect .

D

Both `(A)` and `(R ) ` are incorrect .

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To analyze the assertion and reason given in the question, we will break down the concepts of metal carbonyls and organometallic compounds step by step. ### Step 1: Understanding Metal Carbonyls Metal carbonyls are coordination compounds where a metal is bonded to carbon monoxide (CO) ligands. For example, nickel carbonyl (Ni(CO)4) consists of nickel bonded to four carbon monoxide molecules. **Hint:** Recall that metal carbonyls are characterized by the presence of CO ligands coordinated to a metal center. ### Step 2: Definition of Organometallic Compounds Organometallic compounds are defined as compounds that contain at least one bond between a carbon atom of an organic group and a metal. This means that for a compound to be classified as organometallic, it must have a direct carbon-metal bond with an organic moiety. **Hint:** Remember that organometallic compounds must include an organic group that is directly bonded to the metal. ### Step 3: Analyzing the Assertion The assertion states that "Metal carbonyls can be called organometallics." Since metal carbonyls do not contain any organic groups bonded to the metal, this assertion is incorrect. **Hint:** Consider whether metal carbonyls have any organic groups attached to the metal. ### Step 4: Analyzing the Reason The reason states that "Metal carbonyls do contain metal carbon bonds." This statement is true because metal carbonyls do indeed have metal-carbon bonds, specifically between the metal and the carbon of the CO ligands. **Hint:** Identify whether the presence of metal-carbon bonds alone qualifies a compound as organometallic. ### Step 5: Conclusion Based on the analysis: - The assertion is incorrect because metal carbonyls do not have organic groups and thus cannot be classified as organometallics. - The reason is correct in stating that metal carbonyls contain metal-carbon bonds. Therefore, the correct answer is that the assertion is false, while the reason is true. **Final Answer:** Assertion is false; Reason is true.

To analyze the assertion and reason given in the question, we will break down the concepts of metal carbonyls and organometallic compounds step by step. ### Step 1: Understanding Metal Carbonyls Metal carbonyls are coordination compounds where a metal is bonded to carbon monoxide (CO) ligands. For example, nickel carbonyl (Ni(CO)4) consists of nickel bonded to four carbon monoxide molecules. **Hint:** Recall that metal carbonyls are characterized by the presence of CO ligands coordinated to a metal center. ### Step 2: Definition of Organometallic Compounds ...
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  2. Assertion Metal carbonyls can be called organometallics Reason Metal...

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  3. Assertion A sulphate ion is a biden tate ligand and can also act as mo...

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  4. Assertion: Optical isomerism is not shown by square planar complexes ....

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  5. Assertion In aqueous solution Mohr' s salt gives NH(4)^(o+)Fe^(2+) and...

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  6. Assertion Coordination compounds are generally formed by transition me...

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  7. Assertion Chelates are relatively more stable than non-cheltated compl...

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  8. Assertion The complex [Co(NH(3))(3)CI(3)] gives no precipitate with Ag...

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  9. Ethylenediaminetraac etate ion froms an octo hedral complex with be me...

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  10. Assertion The [Ni(en)(3)]CI(2) (en = ethylenediamine has lower stabili...

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  11. Assertion : NF3 is a weaker ligand than N(Ch3)3 Reason : NF3 ionizes...

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  12. Assertion The total number of isomers shown by [Co(en)(2)CI(2)]^(o+) c...

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  13. Assertion The ligands nitro and nitrito are called ambidenatate Reas...

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  14. Assertion Number of unpaired electrons present in [Cu(NH(3))(2)]^(o+) ...

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  15. Assertion Glycinate ion is an example of monodentate ligand Reason I...

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  16. Assertion The number of unpaired electrons in [Ni(CO)(4)] is zero Re...

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  17. Assertion Ni(CO)(4) is tetrahedral in shape Reason Ni atom is in zer...

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  18. Assertion [M(A A)(3)]^(n+-) is optically inactive Reason Plane of sy...

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  19. Assertion The d(C-O) in bridging carbonyl geroup is longer than that o...

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  20. Assertion A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution of...

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