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Ethylenediaminetraac etate ion froms an ...

Ethylenediaminetraac etate ion froms an octo hedral complex with be metal ion
Reason It has six donor atoms which coordinate simultaneously to the metal ion .

A

If both `(A)` and ` (R )` are correct and `(R )` is the correct explanation of `(A ) ` .

B

If both `(A)` and ` (R )` are correct and `(R )` is the correct explanation of `(A ) ` .

C

If`(A)` is correct, but `( R )` is incorrect .

D

Both `(A)` and `(R ) ` are incorrect .

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The correct Answer is:
To solve the question regarding the formation of an octahedral complex by the ethylenediaminetetraacetate ion (EDTA) with a metal ion, we can break down the explanation into clear steps: ### Step-by-Step Solution: 1. **Understanding EDTA Structure**: - Ethylenediaminetetraacetate (EDTA) is a chelating agent that has a specific structure. It consists of two nitrogen atoms and four carboxylate groups (–COO⁻). - The overall structure can be represented as: ``` H2N-CH2-CH2-NH2 | | | COO⁻ COO⁻ COO⁻ ``` 2. **Identifying Donor Atoms**: - In the EDTA molecule, the two nitrogen atoms each have a lone pair of electrons that can be donated to the metal ion. - Additionally, each of the four carboxylate groups contributes one oxygen atom that can also coordinate to the metal ion. 3. **Counting the Total Donor Atoms**: - The total number of donor atoms in EDTA is calculated as follows: - 2 nitrogen atoms (each donating one pair of electrons) - 4 oxygen atoms from the carboxylate groups (each donating one pair of electrons) - Therefore, the total is: - 2 (from N) + 4 (from O) = 6 donor atoms. 4. **Formation of the Octahedral Complex**: - An octahedral complex requires six donor atoms to surround the central metal ion. - Since EDTA has six donor atoms, it can effectively surround and coordinate with a metal ion, forming a stable octahedral complex. 5. **Conclusion**: - The assertion states that EDTA forms an octahedral complex with a metal ion, and the reason explains that it has six donor atoms that can coordinate simultaneously. - Both the assertion and reason are correct, and the reason provided is a valid explanation for the assertion. ### Final Answer: Both the assertion and reason are correct, and the reason is the correct explanation of the assertion.
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CENGAGE CHEMISTRY ENGLISH-COORDINATION COMPOUNDS-Exercises Assertion Reasoning
  1. Assertion Coordination compounds are generally formed by transition me...

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  2. Assertion Chelates are relatively more stable than non-cheltated compl...

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  3. Assertion The complex [Co(NH(3))(3)CI(3)] gives no precipitate with Ag...

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  4. Ethylenediaminetraac etate ion froms an octo hedral complex with be me...

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  5. Assertion The [Ni(en)(3)]CI(2) (en = ethylenediamine has lower stabili...

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  6. Assertion : NF3 is a weaker ligand than N(Ch3)3 Reason : NF3 ionizes...

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  7. Assertion The total number of isomers shown by [Co(en)(2)CI(2)]^(o+) c...

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  8. Assertion The ligands nitro and nitrito are called ambidenatate Reas...

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  9. Assertion Number of unpaired electrons present in [Cu(NH(3))(2)]^(o+) ...

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  10. Assertion Glycinate ion is an example of monodentate ligand Reason I...

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  11. Assertion The number of unpaired electrons in [Ni(CO)(4)] is zero Re...

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  12. Assertion Ni(CO)(4) is tetrahedral in shape Reason Ni atom is in zer...

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  13. Assertion [M(A A)(3)]^(n+-) is optically inactive Reason Plane of sy...

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  14. Assertion The d(C-O) in bridging carbonyl geroup is longer than that o...

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  15. Assertion A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution of...

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  16. Delta(0) increases in the order of [CrCI(6)]^(3-)lt[Cr(CN)(6)]^(3-)lt[...

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  17. Assertion Hybridisation of [AuCI(4)]^(Θ) is sp^(3) Reason Hybridisat...

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  18. Assertion NO^(o+) has a lower pi accepting tendency than the CO Reas...

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  19. Assertion Complexes containing three bidentate ligands do not show opt...

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  20. AssertionCu^(o+) ion is unstable in aqueous solution, whereas Fe^(2+) ...

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