Home
Class 12
CHEMISTRY
Assertion The [Ni(en)(3)]CI(2) (en = eth...

Assertion The `[Ni(en)_(3)]CI_(2)` (en = ethylenediamine has lower stability than `[Ni(NH_(3))_(6)]CI_(2)`
Reason `In [Ni(en)_(3)]CI_(2)` the geometry of Ni is trigonal bipyramidal .

A

If both `(A)` and ` (R )` are correct and `(R )` is the correct explanation of `(A ) ` .

B

If both `(A)` and ` (R )` are correct and `(R )` is the correct explanation of `(A ) ` .

C

If`(A)` is correct, but `( R )` is incorrect .

D

Both `(A)` and `(R ) ` are incorrect .

Text Solution

AI Generated Solution

To solve the question regarding the stability of the complexes \([Ni(en)_3]Cl_2\) and \([Ni(NH_3)_6]Cl_2\), we will analyze the assertion and reason provided step by step. ### Step 1: Analyze the Assertion The assertion states that \([Ni(en)_3]Cl_2\) has lower stability than \([Ni(NH_3)_6]Cl_2\). - **Stability of Complexes**: The stability of coordination complexes is influenced by the nature of the ligands. Ethylenediamine (en) is a bidentate ligand, while ammonia (NH₃) is a monodentate ligand. Bidentate ligands can form chelate rings, which generally increase the stability of the complex. ### Step 2: Compare the Ligands ...
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Naming And Terminology)|16 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Isomerism)|15 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct (Application Of Coordination Compounds And Miscellaneous)|28 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|23 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos

Similar Questions

Explore conceptually related problems

STATEMENT-1: The [Ni(en)_(3)]Cl_(2) has higher stability than [Ni(NH_(3))_(6)]Cl_(2) and STATEMENT-2: Ethylene diamine shows chelation with Ni^(+2) ion .

The number of geometrical isomers for [Pt(NH_(3))_(2)CI_(2)] is

Calculate the instability constant for [Ni(NH_(3))_(6)]^(2+) , given that beta_(6) for this complex is 2 xx 10^(12)

NiCl_(2)+NH_(3)(excess)to [Ni(NH_(3))_(6)]^(2+)

NiCl_(2)+NH_(3)(excess)to [Ni(NH_(3))_(6)]^(2+)

Number of unpaired electrons present in [Ni(H_(2)O)_(6)]^(3+)

In the conplex [Ni(H_(2)O)_(2)(NH_(3))_(4)]^(2+) the number of unpaired electrons is

The geometry of Ni(CO)_4 and Ni(PPh_3)Cl_2 are

A solution of [Ni(H_(2)O)_(6)]^(2+) is green but a solution of [Ni(CN)_(4)]^(2-) is colourless Explain.

The IUPAC name of [CO(NH_(2))_(6)]CI_(3) is______ .

CENGAGE CHEMISTRY ENGLISH-COORDINATION COMPOUNDS-Exercises Assertion Reasoning
  1. Assertion Coordination compounds are generally formed by transition me...

    Text Solution

    |

  2. Assertion Chelates are relatively more stable than non-cheltated compl...

    Text Solution

    |

  3. Assertion The complex [Co(NH(3))(3)CI(3)] gives no precipitate with Ag...

    Text Solution

    |

  4. Ethylenediaminetraac etate ion froms an octo hedral complex with be me...

    Text Solution

    |

  5. Assertion The [Ni(en)(3)]CI(2) (en = ethylenediamine has lower stabili...

    Text Solution

    |

  6. Assertion : NF3 is a weaker ligand than N(Ch3)3 Reason : NF3 ionizes...

    Text Solution

    |

  7. Assertion The total number of isomers shown by [Co(en)(2)CI(2)]^(o+) c...

    Text Solution

    |

  8. Assertion The ligands nitro and nitrito are called ambidenatate Reas...

    Text Solution

    |

  9. Assertion Number of unpaired electrons present in [Cu(NH(3))(2)]^(o+) ...

    Text Solution

    |

  10. Assertion Glycinate ion is an example of monodentate ligand Reason I...

    Text Solution

    |

  11. Assertion The number of unpaired electrons in [Ni(CO)(4)] is zero Re...

    Text Solution

    |

  12. Assertion Ni(CO)(4) is tetrahedral in shape Reason Ni atom is in zer...

    Text Solution

    |

  13. Assertion [M(A A)(3)]^(n+-) is optically inactive Reason Plane of sy...

    Text Solution

    |

  14. Assertion The d(C-O) in bridging carbonyl geroup is longer than that o...

    Text Solution

    |

  15. Assertion A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution of...

    Text Solution

    |

  16. Delta(0) increases in the order of [CrCI(6)]^(3-)lt[Cr(CN)(6)]^(3-)lt[...

    Text Solution

    |

  17. Assertion Hybridisation of [AuCI(4)]^(Θ) is sp^(3) Reason Hybridisat...

    Text Solution

    |

  18. Assertion NO^(o+) has a lower pi accepting tendency than the CO Reas...

    Text Solution

    |

  19. Assertion Complexes containing three bidentate ligands do not show opt...

    Text Solution

    |

  20. AssertionCu^(o+) ion is unstable in aqueous solution, whereas Fe^(2+) ...

    Text Solution

    |