Home
Class 12
CHEMISTRY
Assertion : NF3 is a weaker ligand than ...

Assertion : `NF_3` is a weaker ligand than `N(Ch_3)_3`
Reason : `NF_3` ionizes to give `F^-` ions in aqueous solution.

A

If both `(A)` and ` (R )` are correct and `(R )` is the correct explanation of `(A ) ` .

B

If both `(A)` and ` (R )` are correct and `(R )` is the correct explanation of `(A ) ` .

C

If`(A)` is correct, but `( R )` is incorrect .

D

Both `(A)` and `(R ) ` are incorrect .

Text Solution

Verified by Experts

The correct Answer is:
C

Correct `(R )` F is highly `EN` it attracts the electrons of `N` towards itself and hence are not easily available on `N` making it a weaker ligand or donor. That is why `NF_(3)` does not ionises to give `F^(Θ)` ions is aqueous solution .
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Naming And Terminology)|16 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Isomerism)|15 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct (Application Of Coordination Compounds And Miscellaneous)|28 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|23 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos

Similar Questions

Explore conceptually related problems

The question consist of two statements each, printed as Assertion and Reason. While answering these questions you are required to choose any one of the following four responses: Assertion: NF_3 is weaker ligand than N(CH_3)_3 . Reason: NF_3 ionizes to give F^(-) ions in aqueous solution.

PH3 is a weaker base than NH3

Assertion : The radius of the first orbit of hydrogen atom is 0.529Å Reason : NF_(3) ionizes to give F^(-1) ions in aqueous solution.

Assertion (A) : N (SiH_3)_3 is a weaker based than N (CH_3)_3 Reason (R) : Due to p pi - d pi back bonding imn N (SiH_3)_3 the availvbaility of electrons on the (B) atom in (SiH_3) N decrease .

Assertion: BF_(3) is weaker lewisi acid than BC l_(3) . Reason: BF_(3) is less electron deficient thann BCl_(3) .

CH_3 CONH_2 is a weaker base than CH_3 CH_2 NH_2 .

Assertion BF_(3) is a weaker Lewis acid than BCI_(3) Reasoning In BF_(3) molecule, back bonding (ppi-ppi) is stronger than in BCI_(3) .

Assertion : Dipole moment of NH_(3) is greater than that of NF_(3) . Reason : Nitrogen is more electronegative than fluorine.

A : NH_(3) is more polar than NF_(3) . R : NF_(3) cannot be hydrolysed .

Dipole moment of NF_(3) is smaller than :

CENGAGE CHEMISTRY ENGLISH-COORDINATION COMPOUNDS-Exercises Assertion Reasoning
  1. Assertion Coordination compounds are generally formed by transition me...

    Text Solution

    |

  2. Assertion Chelates are relatively more stable than non-cheltated compl...

    Text Solution

    |

  3. Assertion The complex [Co(NH(3))(3)CI(3)] gives no precipitate with Ag...

    Text Solution

    |

  4. Ethylenediaminetraac etate ion froms an octo hedral complex with be me...

    Text Solution

    |

  5. Assertion The [Ni(en)(3)]CI(2) (en = ethylenediamine has lower stabili...

    Text Solution

    |

  6. Assertion : NF3 is a weaker ligand than N(Ch3)3 Reason : NF3 ionizes...

    Text Solution

    |

  7. Assertion The total number of isomers shown by [Co(en)(2)CI(2)]^(o+) c...

    Text Solution

    |

  8. Assertion The ligands nitro and nitrito are called ambidenatate Reas...

    Text Solution

    |

  9. Assertion Number of unpaired electrons present in [Cu(NH(3))(2)]^(o+) ...

    Text Solution

    |

  10. Assertion Glycinate ion is an example of monodentate ligand Reason I...

    Text Solution

    |

  11. Assertion The number of unpaired electrons in [Ni(CO)(4)] is zero Re...

    Text Solution

    |

  12. Assertion Ni(CO)(4) is tetrahedral in shape Reason Ni atom is in zer...

    Text Solution

    |

  13. Assertion [M(A A)(3)]^(n+-) is optically inactive Reason Plane of sy...

    Text Solution

    |

  14. Assertion The d(C-O) in bridging carbonyl geroup is longer than that o...

    Text Solution

    |

  15. Assertion A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution of...

    Text Solution

    |

  16. Delta(0) increases in the order of [CrCI(6)]^(3-)lt[Cr(CN)(6)]^(3-)lt[...

    Text Solution

    |

  17. Assertion Hybridisation of [AuCI(4)]^(Θ) is sp^(3) Reason Hybridisat...

    Text Solution

    |

  18. Assertion NO^(o+) has a lower pi accepting tendency than the CO Reas...

    Text Solution

    |

  19. Assertion Complexes containing three bidentate ligands do not show opt...

    Text Solution

    |

  20. AssertionCu^(o+) ion is unstable in aqueous solution, whereas Fe^(2+) ...

    Text Solution

    |