Home
Class 12
CHEMISTRY
Give the number of pair enantiomer of [M...

Give the number of pair enantiomer of `[Ma_(2)b_(2)cd]` .

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of pairs of enantiomers for the coordination compound \([Ma_2b_2cd]\), we will follow these steps: ### Step 1: Identify the Coordination Number and Geometry The coordination compound \([Ma_2b_2cd]\) has a coordination number of 6, which typically indicates an octahedral geometry. **Hint:** Remember that the coordination number indicates how many ligands are attached to the central metal atom. ### Step 2: Determine the Isomer Types In octahedral complexes, we can have different types of isomers, including cis and trans isomers. For the given complex, we need to focus on the cis isomer because only the cis isomer will be optically active (i.e., capable of having enantiomers). **Hint:** Consider how the arrangement of ligands affects the symmetry of the complex. ### Step 3: Draw the Cis Isomer For the cis isomer of \([Ma_2b_2cd]\), we can arrange the ligands as follows: - Place two A ligands adjacent to each other. - Place the B ligand adjacent to one of the A ligands. - Place C and D in the remaining positions. This arrangement will look like this: ``` A / \ B A / \ C D ``` **Hint:** Visualize the arrangement of ligands in 3D to understand how they occupy space around the metal center. ### Step 4: Identify the Mirror Image Next, we need to draw the mirror image of the cis isomer. The mirror image will switch the positions of the ligands, creating a non-superimposable structure. **Hint:** Remember that in a mirror image, left and right positions are swapped. ### Step 5: Count the Pairs of Enantiomers Since we have one cis isomer and its mirror image, we have one pair of enantiomers. Therefore, the number of pairs of enantiomers for the complex \([Ma_2b_2cd]\) is 1. **Hint:** Enantiomers always come in pairs, so count them accordingly. ### Final Answer The number of pairs of enantiomers of \([Ma_2b_2cd]\) is **1**.

To determine the number of pairs of enantiomers for the coordination compound \([Ma_2b_2cd]\), we will follow these steps: ### Step 1: Identify the Coordination Number and Geometry The coordination compound \([Ma_2b_2cd]\) has a coordination number of 6, which typically indicates an octahedral geometry. **Hint:** Remember that the coordination number indicates how many ligands are attached to the central metal atom. ### Step 2: Determine the Isomer Types ...
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Hybridisation , Vbt , Cft And Application)|13 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Fill The Blanks|32 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Naming And Terminology)|16 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|23 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos

Similar Questions

Explore conceptually related problems

A pair of enantiomers is:

Give the ratio of trans- isomers is [M(Aab_(2)c_(2)] (A) and [Ma_(4)b_(2)](B) respectively .

Write the sum of geometrical isomers in [Ma_(2)b_(2)c_(2)] complex and stereoisomers in [M(AB)_(3)] complex .

Co-ordination complexes can show stereoisomerism square planar complexes of Ma_(2)b_(2) type can show geometrical isomerism but not optical & octahedral complexes of Ma_(2)b_(2)C_(2), Ma_(3)b_(3) Mabcdef etc show stereoisomerism, for e.g. Mabcdef have 15 geometrical isomers & all are optically active so it has 15 pairs of enantiomers thus in totaly it has 30 stereoisomers. (a,b,c,d etc. are monodentate lignads while AB is bidenatate ligand) How many pair of enantiomers exits for Ma_(2)b_(2)c_(2) ?

The possible number of stereoismers for the formula [Ma_(2)bcde]^(pmn) .

The number of possible sterio isomers in Ma_(3)b_(3) is equal to (Here a, b are different monodentate ligands).

Which is not the pair of enantiomers ?

An organic compound (A) (C_(10)H_(20)) on reductive ozonolysis gives 2- methyl butanal. Based on this information, answer the following question. If the stereochemistry about the double bound in (A) is cis, the total number of enantiomers for (A) is :

An organic compound (A) (C_(10)H_(20)) on reductive ozonolysis gives 2- methyl butanal. Based on this information, answer the following question. If the stereochemistry about the double bond in (A) is trans, the total number of enantiomers for (A) is :

Select the correct statement for [M(AB)b_(2)cd] .