Home
Class 12
CHEMISTRY
Give the total number of isomer of [Be(g...

Give the total number of isomer of `[Be(gly)_(2)]`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the total number of isomers for the coordination compound \([Be(gly)_2]\), where "gly" represents glycinate (the bidentate ligand), we can follow these steps: ### Step 1: Identify the Coordination Number Beryllium (Be) in this compound has a coordination number of 4 because each glycinate ligand is bidentate, meaning it can bind through two donor atoms (one nitrogen and one oxygen). **Hint:** The coordination number is determined by the number of donor atoms from the ligands that surround the central metal atom. ### Step 2: Determine the Geometry With a coordination number of 4, the geometry of the complex is typically square planar. This is important because the geometry will influence the types of isomers that can exist. **Hint:** The geometry of the complex can help predict the possible arrangements of ligands around the central metal atom. ### Step 3: Analyze the Ligands Glycinate (gly) is a bidentate ligand, meaning it can attach to the metal at two sites. In this case, it binds through nitrogen and oxygen. **Hint:** Bidentate ligands can create different arrangements in the complex, leading to different isomers. ### Step 4: Consider Possible Isomer Types For square planar complexes with bidentate ligands, we can have: - **Cis isomers:** where the two ligands are adjacent to each other. - **Trans isomers:** where the two ligands are opposite each other. In the case of \([Be(gly)_2]\), since the ligands are identical, the arrangement will lead to two distinct isomers: 1. **Cis isomer**: Both glycinate ligands are adjacent. 2. **Trans isomer**: Both glycinate ligands are opposite each other. **Hint:** Identifying the arrangement of identical ligands can help determine the types of isomers present. ### Step 5: Determine Optical Activity In this case, the cis isomer may have a plane of symmetry, making it optically inactive, while the trans isomer may lack a plane of symmetry, making it optically active. **Hint:** The presence or absence of a plane of symmetry can help determine if an isomer is optically active or inactive. ### Conclusion Thus, the total number of isomers for \([Be(gly)_2]\) is 2: one cis isomer and one trans isomer. **Final Answer:** The total number of isomers of \([Be(gly)_2]\) is 2. ---

To determine the total number of isomers for the coordination compound \([Be(gly)_2]\), where "gly" represents glycinate (the bidentate ligand), we can follow these steps: ### Step 1: Identify the Coordination Number Beryllium (Be) in this compound has a coordination number of 4 because each glycinate ligand is bidentate, meaning it can bind through two donor atoms (one nitrogen and one oxygen). **Hint:** The coordination number is determined by the number of donor atoms from the ligands that surround the central metal atom. ### Step 2: Determine the Geometry ...
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Hybridisation , Vbt , Cft And Application)|13 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Fill The Blanks|32 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Naming And Terminology)|16 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|23 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos

Similar Questions

Explore conceptually related problems

Give the total number of possible isomers of [ZnBr_(2)F_(2)]^(2-) .

Give the total number of possible isomers of [Co1_(2)(CN)(NH_(3))en] .

Total number of isomers of C_(4)H_(9)Cl are

Give the number of possibel isomers of [CrCl_(2)en_(2)]^(o+) .

Given the total number of isomers, including stereoisomers, obtained on monochlorination of isopentane.

Given the total number of isomers, including stereoisomers, obtained on dichlorination of paropane.

Give the number of geometrical isomers in [Pt(gly)_(2)] .

Complete catalytic hydrogenation of napthalene gives decalin (C_(10)H_(18)) . The number of isomers of decalin formed and the total number of isomers of decalin possible are respectively.

For the complex [Ma_2B_2] if M is sp^3 or dsp^2 hybridised respectively then total number of optical isomers are respectively: