Home
Class 12
CHEMISTRY
Give the ration of geometrical isomers i...

Give the ration of geometrical isomers in `[M(A A)_(2)b_(2)]` and optical isomers of `[M(A A)_(3)]` .

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of finding the ratio of geometrical isomers in the complex \([M(A A)_{2}B_{2}]\) and optical isomers in the complex \([M(A A)_{3}]\), we will follow these steps: ### Step 1: Analyze the complex \([M(A A)_{2}B_{2}]\) 1. **Identify the ligand arrangement**: The complex has two bidentate ligands \(A\) (denoted as \(AA\)) and two monodentate ligands \(B\). 2. **Determine possible geometrical isomers**: - **Cis form**: Both \(AA\) ligands are adjacent to each other. - **Trans form**: The \(AA\) ligands are opposite each other. Thus, there are **two geometrical isomers**: one cis and one trans. ### Step 2: Analyze the complex \([M(A A)_{3}]\) 1. **Identify the ligand arrangement**: The complex has three bidentate ligands \(A\) (denoted as \(AA\)). 2. **Determine possible optical isomers**: - The arrangement of three bidentate ligands leads to a chiral structure, meaning it can exist in two enantiomeric forms (D and L). - Since there are no planes of symmetry in this arrangement, it will have **two optical isomers**. ### Step 3: Calculate the ratio of geometrical to optical isomers - **Geometrical isomers** in \([M(A A)_{2}B_{2}]\) = 2 - **Optical isomers** in \([M(A A)_{3}]\) = 2 The ratio of geometrical isomers to optical isomers is: \[ \text{Ratio} = \frac{\text{Geometrical Isomers}}{\text{Optical Isomers}} = \frac{2}{2} = 1 \] ### Final Answer The ratio of geometrical isomers in \([M(A A)_{2}B_{2}]\) to optical isomers in \([M(A A)_{3}]\) is **1**. ---

To solve the problem of finding the ratio of geometrical isomers in the complex \([M(A A)_{2}B_{2}]\) and optical isomers in the complex \([M(A A)_{3}]\), we will follow these steps: ### Step 1: Analyze the complex \([M(A A)_{2}B_{2}]\) 1. **Identify the ligand arrangement**: The complex has two bidentate ligands \(A\) (denoted as \(AA\)) and two monodentate ligands \(B\). 2. **Determine possible geometrical isomers**: - **Cis form**: Both \(AA\) ligands are adjacent to each other. - **Trans form**: The \(AA\) ligands are opposite each other. ...
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Hybridisation , Vbt , Cft And Application)|13 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Fill The Blanks|32 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Naming And Terminology)|16 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|23 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos

Similar Questions

Explore conceptually related problems

Give the number of geometrical isomers in [Pt(gly)_(2)] .

Which is the pair of geometrical isomers :

Which can show geometrical isomer ?

Write the sum of geometrical isomers in [Ma_(2)b_(2)c_(2)] complex and stereoisomers in [M(AB)_(3)] complex .

Which is a pair of geometrical isomers?

Which is a pair of geometrical isomers?

Geometrical isomers differ in

Geometrical isomers differ in:

Find the number of geometrical isomers in [Co(en)(Pn)(NO_(2))_(2)] .

Number of geometrical isomers possible of