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Give the ratio of trans- isomers is[M(Aa...

Give the ratio of trans- isomers is`[M(Aab_(2)c_(2)]`(A) and `[Ma_(4)b_(2)](B)` respectively .

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To determine the ratio of trans isomers in the coordination compounds [M(Aa2B2)] (A) and [M(A4B2)] (B), we need to analyze the structure of each complex and identify the possible trans isomers. ### Step-by-Step Solution: 1. **Identify the Ligands and Their Coordination**: - For complex A: [M(Aa2B2)], we have: - M: Metal - Aa: Bidentate ligand (can bind at two sites) - B: Unidentate ligand (binds at one site) - For complex B: [M(A4B2)], we have: - M: Metal - A: Unidentate ligand (binds at one site) - B: Unidentate ligand (binds at one site) 2. **Determine the Possible Trans Isomers for Complex A**: - In [M(Aa2B2)], the bidentate ligand Aa can occupy two coordination sites, leading to different arrangements with the unidentate ligands B. - The two possible trans isomers can be visualized as: - Isomer 1: B and B in trans positions with respect to the bidentate ligand Aa. - Isomer 2: One B and one C in trans positions with respect to the bidentate ligand Aa. - Therefore, there are **2 trans isomers** for complex A. 3. **Determine the Possible Trans Isomers for Complex B**: - In [M(A4B2)], we have four A ligands and two B ligands. - The arrangement can be visualized with B ligands occupying axial positions and A ligands occupying equatorial positions. - Since all A ligands are identical and the B ligands are also identical, there is only **1 trans isomer** for complex B. 4. **Calculate the Ratio of Trans Isomers**: - From the analysis, we have: - Trans isomers in complex A: 2 - Trans isomers in complex B: 1 - Thus, the ratio of trans isomers in [M(Aa2B2)] to [M(A4B2)] is: \[ \text{Ratio} = \frac{2}{1} = 2:1 \] ### Final Answer: The ratio of trans isomers in [M(Aa2B2)] and [M(A4B2)] is **2:1**.

To determine the ratio of trans isomers in the coordination compounds [M(Aa2B2)] (A) and [M(A4B2)] (B), we need to analyze the structure of each complex and identify the possible trans isomers. ### Step-by-Step Solution: 1. **Identify the Ligands and Their Coordination**: - For complex A: [M(Aa2B2)], we have: - M: Metal - Aa: Bidentate ligand (can bind at two sites) ...
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