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Under the influence of strong the ligand...

Under the influence of strong the ligands the electrons can be forced______against the_____ rule of__________ .

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To fill in the blanks in the statement "Under the influence of strong ligands, the electrons can be forced ______ against the ______ rule of ________," we can derive the answer from the explanation provided in the video transcript. ### Step-by-Step Solution: 1. **Identify the Concept**: The question revolves around the behavior of electrons in coordination compounds, specifically when influenced by strong field ligands. 2. **Understand Strong Field Ligands**: Strong field ligands, such as cyanide (CN⁻), have a strong ability to attract electrons and can cause pairing of electrons in the d-orbitals of the metal ion. 3. **Recall Hund's Rule**: Hund's rule states that electrons will fill degenerate orbitals singly first before pairing up, in order to maximize the number of unpaired electrons. 4. **Analyze the Example**: In the example of the complex ion Fe(CN)₆²⁻, the presence of the strong field ligand (CN⁻) leads to the pairing of electrons in the d-orbitals of iron (Fe). Normally, in a d⁶ configuration, there would be unpaired electrons, but the strong field ligand forces them to pair. 5. **Fill in the Blanks**: - The first blank should be "pair up" because the electrons are forced to pair. - The second blank should be "Hund's" because we are referring to Hund's rule. - The third blank should be "maximum multiplicity" because Hund's rule is about maximizing the number of unpaired electrons (multiplicity). ### Final Statement: "Under the influence of strong ligands, the electrons can be forced **pair up** against the **Hund's** rule of **maximum multiplicity**."
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CENGAGE CHEMISTRY ENGLISH-COORDINATION COMPOUNDS-Exercises Fill The Blanks
  1. Coordination isomerism occurs when both cation and anion are .

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  2. The magnitude of stability constant gives an indication of the stabili...

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  3. Under the influence of strong the ligands the electrons can be forceda...

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  4. d(x2),d(yz) and d(zx) orbitals have energies and are collectively term...

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  5. d(xy),d(yz) and d(zx) orbitals have energies and are collectively term...

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  6. Organometallic compounds are those compounds which contain one or more...

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  7. d^(2) sp^(3) hybridisation of the central atom gives the orbital compl...

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  8. Wilkinson's catalyst, unsed as a catalyst in the hydrogenation of alke...

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  9. Recently the platinum complex known as cisplatin has been found in the...

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  10. Ziegker-Natta catalyst, used as a catalyst for the low temperature pol...

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  11. Zeisse's-salt Ferrocene and Dibenzene chromium are the example of bond...

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  12. Calcium dihydrogen salt of EDTA is used as an antidote for the poisoni...

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  13. [Co(NH(3))(5)SO(4)]Br and [Co(NH(3))(5)Br]SO(4) shown isomerism .

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  14. According to valence bond theory the geometry of [Ni(CO)(4)] is .

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  15. K(4)Fe(CO)(6) is considered to a be a complex but potash alum isand bl...

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  16. Grignard reagent is a organometallic compound .

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  17. [Co(NH(3))(6)]^(3+) is diamagnetic while [CoF(6)]^(3-) is .

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  18. [ptabcd]^(n+-) hasshape and has geometrical isomers .

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  19. Geomerical isomerism is not observed in complexes of coordination numb...

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  20. Trans form of [M(A A)(2)a(2)]^(n+) complex does not show isomerism .

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